To improve the sintering performance of silicon nitride bioceramics, we explored the effect of β-SiAlON's Z-value on the physical, chemical, and biological properties of β-SiAlON-SiN composites. Results showed that the phase product was β-SiN. As the Z-value increased, the X-ray diffraction peaks gradually shifted to a smaller angle, the material grains were more tightly packed, and the bulk density and compressive strength increased, reaching the highest values (2.71 g/cm and 1157 MPa, respectively) at Z = 4. Soaking and ion-release experiments show that in an aqueous environment, a small amount of Al and Si ions were released, and no obvious decomposition occurred on the surface of the material. The biological performance showed that the growth of cultured cells in each group was in good condition, there was no obvious difference in morphology and adhesion, and the materials had good biological performance. An increase in the Z-value promotes the formation of mineralized nodules and osteogenic differentiation of MC3T3-E1 cells, which may be because the release of Si can promote osteogenic differentiation. Therefore, the addition of β-SiAlON could improve the sintering performance of β-SiN without degrading its biological properties. The prepared β-SiAlON-SiN composite ceramic is a latent bioceramic material.
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http://dx.doi.org/10.1177/08853282211054323 | DOI Listing |
Energy Fuels
March 2025
Environmental Research Group, Instituto de Carboquímica (Spanish National Research Council, ICB-CSIC), Miguel Luesma Castán 4, 50018 Zaragoza, Spain.
In this work, a detailed parametric study of sorption-enhanced methanation (SEM) to produce synthetic natural gas was carried out. A commercial Ni-based catalyst and CaO as a HO sorbent were used as functional materials. The operational parameters studied included the reaction temperature, H/CO module in the feed gas, CO space velocity, and sorbent/catalyst mass ratio.
View Article and Find Full Text PDFJ Chromatogr A
March 2025
Department of Instrumentation and Analytical Chemistry, CAS Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS), Dalian 116023, China. Electronic address:
In this work, a 3D-printed metal column engineered specifically for micro gas chromatography applications was developed, and an in-depth characterization of its performance and gas separation capabilities were conducted. A microchip gas chromatography column, with dimensions 7.0 × 7.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
March 2025
South China University of Technology, School of Environment and Energy, Room 316, B5 Building, South China University of Technology, Guangzhou Higher Education Mega Center, 510006, Guangzhou, CHINA.
Na4Fe3(PO4)2P2O7 (NFPP) has been considered as a promising cathode material for sodium ion batteries (SIBs). However, the inferior electronic conductivity and inadequate Na+ ions diffusion kinetics of NFPP at low temperatures hinder its practical applications. In this study, high entropy Na4Fe2.
View Article and Find Full Text PDFBiofabrication
March 2025
The Second Hospital of Shandong University, 247 Beiyuan Street, Jinan, Shandong, People's Republic of China, Jinan, 250033, CHINA.
Ultraviolet photopolymerization additive manufacturing has been used to fabricate calcium phosphate (Ca-P) ceramic scaffolds for repairing bone defects, but it is still a challenge for 3D printed Ca-P scaffolds to simultaneously enhance the mechanical strength and osteoinductivity. Here, we successfully developed a high-performance hydroxyapatite (HA) scaffold containing in-situ carbon and graphene oxide (GO) by precisely regulating the degreasing and sintering atmosphere. The results indicated that the mechanical properties of HA scaffolds could be significantly improved by regulating the amount of in-situ carbon.
View Article and Find Full Text PDFLangmuir
March 2025
College of Biological, Chemical Sciences and Engineering, Jiaxing University, 118 Jiahang Road, Jiaxing 314001, China.
The strong metal-support interaction (SMSI) plays a crucial role in heterogeneous catalytic reactions. In this study, we introduced a carbon nanofiber-assisted method to adjust the Ni-CeO interaction. The catalysts' physicochemical properties were characterized using various techniques and their performance was evaluated in acetic acid steam reforming.
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