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In-depth understanding of local soil chemistry reveals that addition of Ca may counteract the mobilisation of Ra and other pollutants before wetland creation on the Grote Nete river banks. | LitMetric
The "Sigma plan" https://www.sigmaplan.be/en/ aims to create in Belgium inundation zones along the Grote Nete river to prevent Antwerp from flooding in extreme weather conditions. The riverbanks of the Grote Nete are at some hotspots historically contaminated by the phosphate industry resulting in Naturally Occurring Radionuclides (NOR) legacy. Ra is from a radiation protection point of view one of the most important radionuclides present at the hot spot under study, with a local soil activity concentration higher than 3000 Bq/kg Ra. In this paper, we identify the most relevant mechanisms governing the mobility of Ra. We selected for this study the role of CaSO.2HO, clay minerals and humic acids as the main contributors determining the speciation of Ra, due to their presence at the hot spot, their cation exchange capacity and their functional group density, respectively. Various novel analytical chemistry approaches were developed to study the prevailing reaction mechanisms that impact the solid-liquid distribution of Ra. We show that Ra coprecipitates in a (Ca,Ra)SO solid solution due to the high Ca and SO concentrations in the local hot spot. If CaSO.2HO is not saturated in the soil solution, Ra adsorption to clay minerals counteracts the tendency of Ra partitioning to the liquid phase by interactions with humic and fulvic acids. Interactions between different soil compounds may further alter the partitioning of Ra. As, Cd, Pb and Zn in the hot spot are significantly above background values in Flemish sediments. Pb may be coprecipitated as sulphate salts, whereas Cd and Zn are most probably partially present as arsenate salts. The excess of Zn may interact with humic acids. The observed reaction mechanisms suggest that Ca might play a key role in the immobilisation of Ra. The role of Ca as immobilisation agent of the other contaminants is discussed.
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