Rotationally resolved spectra of the ÃA-X̃A origin bands for both trans- and cis-conformers of 1-vinylpropargyl radical (1VPR) are experimentally studied. Rotational constants for both ground and electronically excited states are experimentally determined. The stability of the ÃA excited state of the cis-1VPR is found to be higher than that of trans-1VPR, which is likely due to additional π-overlap and increased p electron delocalization in the excited state of cis-1VPR.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1063/5.0078580 | DOI Listing |
Publication Analysis
Top Keywords
excited state
8
state cis-1vpr
8
high-resolution laser
4
laser spectroscopy
4
spectroscopy trans-
4
trans- cis-1-vinylpropargyl
4
cis-1-vinylpropargyl radicals
4
radicals rotationally
4
rotationally resolved
4
resolved spectra
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!