A catalyst-induced defluorinative, alkylation or metal-free hydroalkylation of -difluoroalkenes enabled by visible light was developed. This protocol provided a mild and practical approach to important and novel monofluoroalkenes and difluoromethylene-containing compounds with moderate to excellent yields.
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http://dx.doi.org/10.1021/acs.joc.1c02662 | DOI Listing |
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