Dye-sensitized solar cells (DSSCs) were devised with the sensitizers prepared from the leaves and flowers of Amaranthus cruentus. Fresh and dried leaves were employed for extracting the dye sensitizers. Acetone, ethanol, and deionized water were used as solvents for the extraction process. A sum of nine dyes was prepared. For all the extracted dyes, spectroscopic studies (UV-visible & FTIR) were performed to ensure that the dyes are suitable to be used as sensitizers for DSSC. XRD and SEM were recorded for the TiO paste used. Nine DSSCs were fabricated with the extracted dyes as sensitizers, TiO as semiconductor oxide, I/I as electrolyte, and graphene-coated FTO as counter electrode. J-V characterization study was done for each cell showed that the cell with dye taken from the fresh leaves using acetone exhibited the highest efficiency of 0.816%. It was noted that these cells recorded higher efficiency than the previously reported works with dyes taken from Amaranthus red.
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http://dx.doi.org/10.1007/s11356-022-19004-5 | DOI Listing |
Chem Commun (Camb)
January 2025
Department of Chemistry, Khalifa University, SAN Campus, Abu Dhabi, United Arab Emirates.
During the process of developing smart chiroptical luminophores, small chiral organic dyes have emerged as candidates of utmost importance. In this regard, the chiral variants of boron dipyrromethene (BODIPY) serve as suitable molecules owing to their excellent photophysical properties such as high fluorescence quantum yields, narrow emission bandwidths with high peak intensities, high photo and chemical stability, and higher molar extinction coefficients. Thus, the last decade observed an influx of research from various research groups for the induction of chirality in originally achiral BODIPY.
View Article and Find Full Text PDFTop Curr Chem (Cham)
December 2024
Department of Chemistry, King Khalid University, P.O. Box 9004, 61413, Abha, Saudi Arabia.
Carbazoles are nitrogen-containing aromatic heterocycles, having widespread applications in the field of photovoltaics. Carbazole-based photosensitizers have tunable features for absorption on semi-conductor (tellurium dioxide or zinc oxide) layers to create sufficient push-pull force in the conversion of sunlight into electrical energy, thus presenting as promising heterocyclic donor candidates to be used in dye-sensitized solar cells. For the synthesis of these dyes, various structural designs are available, namely, D-A, D-π-A, D-D-π-A, D-A-π-A, A-π-D-π-A-π-A, and D2-π-A that all involve incorporating carbazole as a donor (D), along with spacer (π-extender) moieties, such as thiophene, phenol, ethynylene, nitromethane, azine, thiadiazole, or acetonitrile.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
Department of Chemistry, Faculty of Science, Al-Azhar University, Nasr City, Cairo 11884, Egypt. Electronic address:
The quick and precise estimation of D-π-A Organic Dye absorption maxima in different solvents is an important challenge for the efficient design of novel chemical structures that could improve the performance of dye-sensitized solar cells (DSSCs) and related technologies. Time-Dependent Density Functional Theory (TD-DFT) has often been employed for these predictions, but it has limitations, including high computing costs and functional dependence, particularly for solvent interactions. In this study, we introduce a high-accuracy and rapid deep-learning ensemble method using daylight fingerprints as chemical descriptors to predict the absorption maxima (λ) of D-π-A organic dyes in 18 different solvent environments.
View Article and Find Full Text PDFDalton Trans
December 2024
Energy Materials Laboratory, Chemistry, School of Natural and Environmental Sciences, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK.
This article reports the development of CuO|CuBiO photocathodes stabilized by protective layers of TiO, MgO, or NiO, with Pt or MoS nanoparticles serving as co-catalysts to facilitate H evolution. Most notably, this work demonstrates the first application of MgO as a protection/passivation layer for photocathodes in a water-splitting cell. All configurations of photocathodes were studied structurally, morphologically, and photoelectrochemically revealing that CuO|CuBiO|MgO|Pt photocathodes achieve the highest stable photocurrent densities of -200 μA cm for over 3 hours with a Faradaic efficiency of ∼90%.
View Article and Find Full Text PDFBeilstein J Org Chem
November 2024
School of Chemistry and Forensic Science, University of Kent, Canterbury, CT2 7NH, UK.
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