The photocatalytic degradation of paracetamol (a common analgesic also known as acetaminophen) in ultrapure water with different photocatalytic systems was performed under ultraviolet or visible irradiation. The photocatalysts employed were: commercial Degussa-P25 TiO and Au-TiO under UVA irradiation (365 nm) and g-CN and Au-g-CN under visible light irradiation (low-power (4 × 10 W) white light LEDs), improving the effectiveness of degradation rates when the gold nanoparticles (Au NPs) were combined with the semiconductors. The nanostructured photocatalysts were synthesised and characterised by transmission electron microscope (TEM), UV-vis diffuse reflectance spectroscopy and, in the case of g-CN photocatalysts by X-ray photoelectron spectroscopy (XPS). The influence of the pH in the depletion of paracetamol with g-CN and visible light was evaluated. In addition, the stability and lifetime of the photocatalyst g-CN in the degradation of paracetamol were studied.
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http://dx.doi.org/10.1007/s43630-022-00172-9 | DOI Listing |
Chem Soc Rev
January 2025
National-local Joint Engineering Research Center of Biomass Refining and High-quality Utilization, Changzhou University, Changzhou 213164, China.
Multiple oxygenate groups in biomass-based feedstocks are open to multiple catalytic pathways and products, typically resulting in low selectivity for the desired products. In this context, strategies for rational catalyst design are critical to obtain high selectivity for the desired products in biomass upgrading. The Sabatier principle provides a conceptual framework for designing optimal catalysts by following the volcanic relationship between catalyst activity for a reaction and the binding strength of a substrate on a catalyst.
View Article and Find Full Text PDFInvest Ophthalmol Vis Sci
January 2025
Vitreous Retina Macula Consultants of New York, New York, United States.
Purpose: The purpose of this study was to develop ground-truth histology about contributors to variable fundus autofluorescence (FAF) signal and thus inform patient selection for treating geographic atrophy (GA) in age-related macular degeneration (AMD).
Methods: One woman with bilateral multifocal GA, foveal sparing, and thick choroids underwent 535 to 580 nm excitation FAF in 6 clinic visits (11 to 6 years before death). The left eye was preserved 5 hours after death.
Chaos
January 2025
State Key Laboratory of Mechanics and Control for Aerospace Structures, College of Aerospace Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China.
The aircraft can experience complex environments during the flight. For the random actions, the traditional Gaussian white noise assumption may not be sufficient to depict the realistic stochastic loads on the wing structures. Considering fluctuations with extreme conditions, Lévy noise is a better candidate describing the stochastic dynamical behaviors on the airfoil models.
View Article and Find Full Text PDFMol Divers
January 2025
School of Life Sciences, Jilin University, 2699 Qianjin Street, Changchun, 130012, People's Republic of China.
The 2-substituted benzimidazole has emerged as a promising heterocyclic compound in the field of drug design. In pursuit of more sustainable photocatalysts for 2-substituted benzimidazole synthesis, the method for coating FeO with V-doped TiO was presented. On the base of characterizing composition, morphology, and properties, the prepared nano-sized FeO@V/TiO composites were used as a heterogeneous photocatalyst to catalyze the synthesis of 2-substituted benzimidazoles under light.
View Article and Find Full Text PDFAnal Sci
January 2025
Department of Analytical Chemistry, Faculty of Pharmacy, Near East University, TRNC, Mersin 10, 99138, Nicosia, Turkey.
In this research, a green approach utilizing deep eutectic solvent liquid-liquid microextraction is combined with smartphone digital image colorimetry for the determination of boron in nut samples. A smartphone camera was used to capture the image of the analyte extract located in a custom-made colorimetric box. Using ImageJ software, the images were split into RGB channels, with the green channel identified as the optimum.
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