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Temperature-dependent excitonic emission characteristics of lead-free inorganic double perovskites and their third-order optical nonlinearities. | LitMetric

AI Article Synopsis

Article Abstract

We report temperature-dependent photoluminescence (PL) in the temperature range between 77 K and 300 K, and room temperature nonlinear optical (NLO) properties of solution processed lead-free CsNaBiI (CNBI) and CsKBiI (CKBI) perovskite films. The de-convolution analysis of temperature-dependent PL spectra showed thermal quenching behavior of free-exciton (FX) emission, an unusual blue-shift of PL emission, and line broadening with increasing temperature as a consequence of strong exciton-phonon interaction. The nonlinear refractive index () and nonlinear absorption coefficient () of both the CNBI and CKBI films are determined using a closed aperture (CA) and open aperture (OA) Z-scan technique, respectively. Both the CNBI and CKBI perovskites exhibited features of saturable absorption (SA) with ∼ -6.23 × 10 cm W, and -1.14× 10 cm W, respectively. The CA measurements depicted a self-defocusing effect in both the samples with values ∼-1.06 × 10 cm W and -1.337× 10 cm W, respectively. With such emission and NLO characteristics, CNBI and CKBI perovskite films can be used for designing eco-friendly optoelectronic and NLO devices.

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http://dx.doi.org/10.1039/d1cp04896aDOI Listing

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