Utilization and recycling of wood ashes from industrial heat and power plants regarding fertilizer use.

To achieve a sustainable circular economy for wood ash, the reuse of wood ash in agriculture and forestry is important. To evaluate the usability of ash from the combustion of natural as well as waste wood for application as fertilizer, wood fuel and corresponding ash fraction samples (n = 86) of four industrial wood-fired heat and power plants (>20 MW) were investigated. In different ash fractions, the concentrations of heavy metals (As, Cd, Pb, Ni, Tl, Zn) and plant nutrients (N, P, K, Ca) were assessed with regard to relevant legislation from the European Union and from selected European countries (Germany, Austria and Finland). Depending on fuel composition and combustion kinetics within the respective plants, the investigated ash fractions showed a wide range of nutrient and heavy metal contents. Apart from N which is mainly emitted with the flue gas, plant nutrients were present in substantial concentrations with mean values corresponding to 20% P, 55 % K and >95% Ca content compared to nutrient compound fertilizer. A direct application of most ash fractions from both natural and waste wood combustion is however not possible due to high contents of Cd, Pb and Ni. In order to develop the ash for secondary use, investigation for a suitable treatment process is necessary. An estimation of the nutrient recovery potential from industrial wood energy plants in southwest Germany showed that approx. 3.1% (P), 7.5% (K) and 22.8% (Ca) of raw material for fertilizers could be substituted by ash.