We demonstrate that allosteric effects and redox state changes can be harnessed to create a switch that selectively and reversibly regulates the coordination chemistry of a single site on the surface of a molecular cluster. This redox-switchable allostery is employed as a guiding force to assemble the molecular clusters ZnCoSeL' (L' = PhPN(H)Tol, Ph = phenyl, Tol = 4-tolyl) into materials of predetermined dimensionality (1- or 2-D) and to encode them with emissive properties. This work paves the path to program the assembly and function of inorganic clusters into stimuli-responsive, atomically precise materials.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8790731 | PMC |
| http://dx.doi.org/10.1021/jacsau.1c00491 | DOI Listing |
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