A rhodamine based dual chemosensor for Al and Hg: Application in the construction of advanced logic gates.

A rhodamine-based compound (RBO), which has been constructed from the reaction between N-(rhodamine-6G)lactam-ethylenediamine and 2,1,3-benzoxadiazole-4-carbaldehyde, is reported here as a selective chemosensor for both Al and Hg ions in 10 mM HEPES buffer in water:ethanol (1:9, pH = 7.4). Absorption intensity of RBO increases considerably at 528 nm with these cations. It shows fluorescence enhancement at 550 nm by 1140- and 524-fold in the presence of Al and Hg, respectively. LOD has been determined as 6.54 and 16.0 nM for Al and Hg, respectively. Quantum yield and lifetime of RBO enhances with these metal ions. Fluorescence intensity of Al-probe complex or Hg-probe complex is quenched in the presence of fluoride or sulfide ion, respectively, opening a path for the construction logic gates. DFT analysis has been used to understand the spectral transitions. We have constructed a systematic development from single to five inputs complex circuit, and for the first time a time dependent five input complex logic circuit is reported herein.