In one-dimensional quantum gases there is a well known "duality" between hard core bosons and noninteracting fermions. However, at the field theory level, no exact duality connecting strongly interacting bosons to weakly interacting fermions is known. Here we propose a solution to this long-standing problem. Our derivation relies on regularizing the only pointlike interaction between fermions in one dimension that induces a discontinuity in the wave function proportional to its derivative. In contrast to all known regularizations our potential is weak for small interaction strengths. Crucially, this allows one to apply standard methods of diagrammatic perturbation theory to strongly interacting bosons. As a first application we compute the finite temperature spectral function of the Cheon-Shigehara model, the fermionic model dual to the celebrated Lieb-Liniger model.
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http://dx.doi.org/10.1103/PhysRevLett.128.021604 | DOI Listing |
Langmuir
December 2024
Department of Physics, National Institute of Technology, Jamshedpur-831014, India.
We have conducted a systematic study employing density functional theory (DFT) and quantum theory of atoms in molecules (QTAIM) to explore the gas sensing capabilities of nitrogen-doped single vacancy graphene quantum dots (SV/3N) decorated with transition metals (TM = Mn, Co, Cu). We have studied the interactions between TM@SV/3N and four different target gases (AsH, NH, PH, and HS) through the computation of adsorption energies, charge transfer, noncovalent interaction, density of states, band gap, and work function for 12 distinct adsorption systems. Our comprehensive analysis included an in-depth assessment of sensors' stability, sensitivity, selectivity, and reusability for practical applications.
View Article and Find Full Text PDFLuminescence
December 2024
Department of Chemistry and Chemical Engineering, College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin, China.
Herein, a kind of N-doped fluorescent carbon dots (N-CDs) were prepared by using melamine and carboxymethyl cellulose (CMC) as precursors through a straightforward hydrothermal method. The designed sensor displayed a uniform nanoscale distribution, excellent hydrophilicity, and strong fluorescence emission with a fluorescence quantum yield of 37.98%.
View Article and Find Full Text PDFJ Am Chem Soc
December 2024
School of Chemistry, University of New South Wales, Kensington, NSW 2052, Australia.
Hydrofluoroolefins (HFOs) and hydrochlorofluoroolefins (HCFOs) are the leading synthetic replacements for compounds successively banned by the Montreal Protocol and amendments. HFOs and HCFOs readily decompose in the atmosphere to form fluorinated carbonyls, including CFCHO in yields of up to 100%, which are then photolyzed. A long-standing issue, critical for the transition to safe industrial gases, is whether atmospheric decomposition of CFCHO yields any quantity of CHF (HFC-23), which is one of the most environmentally hazardous greenhouse gases.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Departament de Física, Campus Nord B4-B5, Universitat Politècnica de Catalunya, E-08034 Barcelona, Spain.
We predict that ultracold bosonic dipolar gases, confined within a multilayer geometry, may undergo self-assembling processes, leading to the formation of chain gases and solids. These dipolar chains, with dipoles aligned across different layers, emerge at low densities and resemble phases observed in liquid crystals, such as nematic and smectic phases. We calculate the phase diagram using quantum Monte Carlo methods, introducing a newly devised trial wave function designed for describing the chain gas, where dipoles from different layers form chains without in-plane long-range order.
View Article and Find Full Text PDFFront Chem
December 2024
College of Engineering and Technology, Southwest University, Chongqing, China.
Detecting dissolved gases in transformer oil is crucial for assessing the operational status of transformers. The gas composition in transformer oil can reflect the health status of the equipment and help identify potential failure risks in a timely manner. Based on density functional theory (DFT), Pd and Rh atoms were doped into the h-BN monolayer, and the most stable adsorption structures for each were first explored.
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