Soil organic carbon (SOC) concentration is the fundamental indicator of soil health, underpinning food production and climate change mitigation. SOC storage is highly sensitive to several dynamic environmental drivers, with approximately one third of soils degraded and losing carbon worldwide. Digital soil mapping illuminates where hotspots of SOC storage occur and where losses to the atmosphere are most likely. Yet, attempts to map SOC often disagree. Here we compare national scale SOC concentration map products to reveal agreement of data in mineral soils, with progressively poorer agreement in organo-mineral and organic soils. Divergences in map predictions from each other and survey data widen in the high SOC content land types we stratified. Given the disparities are highest in carbon rich soils, efforts are required to reduce these uncertainties to increase confidence in mapping SOC storage and predicting where change may be important at national to global scales. Our map comparison results could be used to identify SOC risk where concentrations are high and should be conserved, and where uncertainty is high and further monitoring should be targeted. Reducing inter-map uncertainty will rely on addressing statistical limitations and including covariates that capture convergence of physical factors that produce high SOC contents.
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http://dx.doi.org/10.1038/s41598-022-05476-5 | DOI Listing |
Chem Soc Rev
January 2025
Birmingham Centre for Energy Storage & School of Chemical Engineering, University of Birmingham, UK.
This review explores the behavior of low-concentration CO (LCC) in various energy media, such as solid adsorbents, liquid absorbents, and catalytic surfaces. It delves into the mechanisms of diffusion, adsorption, and catalytic reactions, while analyzing the potential applications and challenges of these properties in technologies like air separation, compressed gas energy storage, and CO catalytic conversion. Given the current lack of comprehensive analyses, especially those encompassing multiscale studies of LCC behavior, this review aims to provide a theoretical foundation and data support for optimizing CO capture, storage, and conversion technologies, as well as guidance for the development and application of new materials.
View Article and Find Full Text PDFAdv Mater
January 2025
Key Laboratory of Power Station Energy Transfer Conversion and System of Ministry of Education and School of Energy Power and Mechanical Engineering, and Beijing Laboratory of New Energy Storage Technology, North China Electric Power University, Beijing, 102206, China.
Co-free high-Ni layered cathode materials LiNiMeO (Me = Mn, Mg, Al, etc.) are a key part of the next-generation high-energy lithium-ion batteries (LIBs) due to their high specific capacity and low cost. However, the hindered Li kinetics and the high reactivity of Ni result in poor rate performance and unsatisfied cycling stability.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Nanoyang Group, Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, School of Chemical Engineering and Technology, National Industry-Education Integration Platform of Energy Storage, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, China.
In situ polymerization strategies hold great promise for enhancing the physical interfacial stability in solid-state batteries, yet (electro)chemical degradation of polymerized interfaces, especially at high voltages, remains a critical challenge. Herein, we find interphase engineering is crucial for the polymerization process and polymer stability and pioneer an in situ polymerization-fluorination (Poly-FR) strategy to create durable interfaces with excellent physical and (electro)chemical stabilities, achieved by designing a bifunctional initiator for both polymerization and on-surface lithium donor reactions. The integrated in situ fluorination converts LiCO impurities on LiNiCoMnO (NCM811) surfaces into LiF-rich interphases, effectively inhibiting the aggressive (de)lithiation intermediates and protecting the interface from underlying chemical degradation, thereby surpassing the stability limitations of polymerization alone.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Engineering Research Center of Advanced Rare Earth Materials, Department of Chemistry, Tsinghua University, Beijing 100084, China.
The side reactions accompanying the charging and discharging process, as well as the difficulty in decomposing the discharge product lithium peroxide, have been important issues in the research field of lithium-oxygen batteries for a long time. Here, single atom Ta supported by CoO hollow sphere was designed and synthesized as a cathode catalyst. The single atom Ta forms an electron transport channel through the Ta-O-Co structure to stabilize octahedral Co sites, forming strong adsorption with reaction intermediates and ultimately forming a film-like lithium peroxide that is highly dispersed.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Zhejiang Key Laboratory of Excited-State Energy Conversion and Energy Storage, and Department of Chemistry, Zhejiang University, Hangzhou 310058, China.
Here, we demonstrate that monocrystalline (free of stacking faults) wurtzite CdSe nanocrystals with monodisperse size, shape (dots, rods, or wires), and facet structure are synthesized in both strongly confined and weakly confined size regimes. Considering the unique -axis of wurtzite CdSe, we introduce a new type of neutral ligand (e.g.
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