Highly wetting and nonwetting substrates have been widely used in fogwater collection systems for enhanced water harvesting. In this work, fog harvesting substrates comprising PVC strips of different wetting properties and widths ranging from 1-5 mm were vertically aligned and spaced apart at regular intervals to give the same solid area fraction of 0.8. Evaluation of the water collection efficiencies of the tested configurations revealed that 1 mm wide superhydrophilic strips was the most efficient, achieving double the amount of water harvested compared with 2.8 mm wide strips. This finding was attributed to the low Stokes numbers of the aerosol particle distribution of the fog which tended to result in them being brought by the flow streamlines toward the air gaps between the strips. Stagnant flow regions at the edges of each strip, revealed through potential flow calculations, then caused higher liquid imbibition and impaction there for water harvesting. It was also found that the Cassie nonwetting substrates that originally exhibited contact angles of 161° transformed to Wenzel wetting with zero contact angle within 60 min of fog interception. Optical profilometry revealed no obvious difference in surface roughness between the central region and edges of the strips, indicating that surface morphology was unlikely to be a contributing factor for enhanced water collection at the edges. The findings here indicated that highly wetting vertical strip architectures with narrow widths (1 mm) were favorable over wider strips for water harvesting provided that clogging and re-entrainment were not significant factors.
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http://dx.doi.org/10.1021/acs.langmuir.1c02965 | DOI Listing |
Water Res
December 2024
School of Environmental Science and Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, Shanghai, PR China. Electronic address:
Dense Janus membranes (JMs) are potential candidates in hypersaline wastewater treatments for membrane distillation (MD). However, dense surface layers generally add obvious membrane mass transfer resistance, limiting its practical application. In this study, a novel dense JM was facilely developed by controlled interfacial polymerization utilizing a phosphonium functional monomer (THPC) on hydrophilic polyvinylidene fluoride (PVDF) substrate.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Advanced Functional Nanomaterials Research Laboratory, Centre for Nanoscience and Technology, Madanjeet School of Green Energy Technologies, Pondicherry University (A Central University), Dr. R. Venkataraman Nagar, Kalapet, Puducherry 605014, India.
The development of quasi-solid-state lithium metal batteries (QSSLMBs) is hindered by inadequate interfacial contact, poor wettability between electrodes and quasi-solid-state electrolytes, and significant volume changes during long-term cycling, leading to safety risks and cataclysmic failures. Here, we report an innovative approach to enhance interfacial properties through the construction of QSSLMBs. A multilayer design integrates a microwave-synthesized LiAlTi(PO) (LATP) ceramic electrolyte, which is surface-coated with a lithiophilic conductive ink comprising VS and disulfonated functionalized graphene nanosheets (VS-DSGNS) using a low-cost nail-polish binder.
View Article and Find Full Text PDFSmall Methods
December 2024
The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials (MoE), National Engineering Laboratory of Eco-Friendly Polymeric Materials (Sichuan), State Key Laboratory of Polymer Materials Engineering, College of Chemistry, Sichuan University, Chengdu, 610064, China.
Developing superwetting coatings with environmental adaptability is critical for sustainable industrial applications. However, traditional anti-wetting coatings often fall short due to their susceptibility to environmental factors (UV light, temperature, mold growth, and abrasion) and inadequate stain resistance in complex media. Herein, a durable ex situ pH-responsive coating with reversible wettability switching, engineered by integrating hydrophobic polydimethylsiloxane and tertiary amine structures is presented.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
GISC, Departamento de Matemáticas, Universidad Carlos III de Madrid, 28911 Leganés, Madrid, Spain.
Recent studies of wetting in a two-component square-gradient model of interfaces in a fluid mixture, showing three-phase bulk coexistence, have revealed some highly surprising features. Numerical results show that the density profile paths, which form a tricuspid shape in the density plane, have curious geometric properties, while conjectures for the analytical form of the surface tensions imply that nonwetting may persist up to the critical end points, contrary to the usual expectation of critical point wetting. Here, we solve the model exactly and show that the profile paths are conformally invariant quartic algebraic curves that change genus at the wetting transition.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
School of Materials Science and Technology, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, China University of Geosciences, Beijing 100083, People's Republic of China.
Lithium-sulfur (Li-S) batteries stand out as highly promising energy storage systems because of their superior theoretical capacity and the affordability of sulfur as an active material. However, their inherent drawbacks have hindered the commercialization of Li-S batteries. Of these, the polysulfide shuttle effect is one of the most critical issues, leading to the rapid decline in battery capacity.
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