The air- and moisture-sensitive title compound, [Tb(CH)(CHNO)], was synthesized from tris-(cyclo-penta-dien-yl)(tetra-hydro-furan)-terbium and 2-{[(2-meth-oxy-phen-yl)imino]-meth-yl}phenol. Each Tb atom is coordinated by two cyclo-penta-dienyl ligands in an η-coordination mode and by one N and two O atoms of the organic ligand in a tridentate κ ,,'-mode.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8739212 | PMC |
| http://dx.doi.org/10.1107/S2056989021013025 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Bis(η-cyclo-penta-dien-yl)(2-{[(2-meth-oxy-phen-yl)imino]-meth-yl}phenolato-κ ,,')terbium.
Acta Crystallogr E Crystallogr Commun
January 2022
Chemistry Department, M.V. Lomonosov Moscow State University, 1 Leninskie Gory, Str., Building 3, Moscow, 119991, Russian Federation.
The air- and moisture-sensitive title compound, [Tb(CH)(CHNO)], was synthesized from tris-(cyclo-penta-dien-yl)(tetra-hydro-furan)-terbium and 2-{[(2-meth-oxy-phen-yl)imino]-meth-yl}phenol. Each Tb atom is coordinated by two cyclo-penta-dienyl ligands in an η-coordination mode and by one N and two O atoms of the organic ligand in a tridentate κ ,,'-mode.
View Article and Find Full Text PDFCrystal structures of two mononuclear complexes of terbium(III) nitrate with the tripodal alcohol 1,1,1-tris-(hy-droxy-meth-yl)propane.
Acta Crystallogr E Crystallogr Commun
February 2017
School of Chemistry, University of East Anglia, University Plain, Norwich NR4 7TJ, UK.
Two new mononuclear cationic complexes in which the Tb ion is bis-chelated by the tripodal alcohol 1,1,1-tris-(hy-droxy-meth-yl)propane (H, CHO) were prepared from Tb(NO)·5HO and had their crystal and mol-ecular structures solved by single-crystal X-ray diffraction analysis after data collection at 100 K. Both products were isolated in reasonable yields from the same reaction mixture by using different crystallization conditions. The higher-symmetry complex dinitratobis[1,1,1-tris-(hy-droxy-meth-yl)propane]-terbium(III) nitrate di-meth-oxy-ethane hemisolvate, [Tb(NO)(H)]NO·0.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!