Distinguishing Thermal from Nonthermal ("Hot") Carriers in Illuminated Molecular Junctions.

Nano Lett

School of Electrical and Computer Engineering, Ben-Gurion University of the Negev, Be'er Sheva 8410501, Israel.

Published: March 2022

The search for the signature of nonthermal (so-called "hot") electrons in illuminated plasmonic nanostructures requires detailed understanding of the nonequilibrium electron distribution under illumination, as well as a careful design of the experimental system employed to distinguish nonthermal electrons from thermal ones. Here, we provide a theory for using plasmonic molecular junctions to achieve this goal. We show how nonthermal electrons can be measured directly and separately from the unavoidable thermal response and discuss the relevance of our theory to recent experiments.

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http://dx.doi.org/10.1021/acs.nanolett.1c04291DOI Listing

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