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Energy saving and emission reduction have always been the goal of separation and catalysis pursued in industrial production. Metal-organic frameworks (MOFs) are leading porous crystal materials with unique advantages in these fields. Based on an amide-modified ligand 5-(ethyl oxamate)-isophthalic acid (HEtL), a new porous indium-organic framework (MeNH)[InL]·2DMF·2HO () was synthesized and structurally characterized. The unique porous environment gives it dual functional advantages in separation and catalysis. At room temperature, possesses excellent adsorption capacities for C hydrocarbons and CO, showing good separation behaviors for C hydrocarbons/CO on CH and CH on CO, which is conducive to efficient purification of CH and CH confirmed by the breakthrough experiment. Meanwhile, catalytic results indicate that can be used as a good catalyst for effective fixation of CO under mild conditions to form cyclic carbonates.
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| http://dx.doi.org/10.1021/acs.inorgchem.1c03821 | DOI Listing |
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