The formation of a stable gas cavity on the surfaces of solid bodies is essential for many practical applications, such as drag reduction and energy savings, owing to the transformation of the originally sticky solid-liquid interface into a free-slip liquid-vapor interface by the creation of either liquid repellency or a Leidenfrost state on the surfaces. Here, it is shown that the simple infusion of a textured sphere with a smooth, slippery liquid layer can more easily create and sustain a stable gas cavity in a liquid at lower impact velocities compared to a dry solid sphere with the same contact angle. With a key parameter of curvature ratio, the early lamella dynamics during water entry of spheres and drops impact on planes are first unified. With the perspective of wetting transition, the unforeseen phenomenon of prone to cavity formation are successfully explained, which is the preferential lamella detachment from a slippery surface due to the higher viscosity of the lubricant relative to air. It is envisioned that the findings will provide an important and fundamental contribution to the quest for energy-efficient transport.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8895157 | PMC |
http://dx.doi.org/10.1002/advs.202103568 | DOI Listing |
Heliyon
July 2024
School of Petroleum Engineering, Chongqing University of Science & Technology, Chongqing, 401331, China.
City gas stations (CGSs) play a crucial role in ensuring a stable and safe supply of natural gas to urban users. However, as the service time of stations increases and the performance of components deteriorates, concerns about the safety and reliability of these station have grown among operators and local government authorities. This paper proposes a fuzzy reliability assessment methodology for CGSs that considers the polymorphism of component faults and the uncertainties associated with fault relationships, failure probabilities, and fault magnitudes.
View Article and Find Full Text PDFNarra J
December 2024
Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Erciyes University, Kayseri, Turkey.
The therapeutic potential of bitter leaf ( Del.) has been established both empirically and in various scientific investigations. However, the molecular pathways related to its possible anti-inflammatory and antioxidant properties remain unclear.
View Article and Find Full Text PDFNature
January 2025
Institut für Organische Chemie, Universität Würzburg, Würzburg, Germany.
Graphene is a single-layered sp-hybridized carbon allotrope, which is impermeable to all atomic entities other than hydrogen. The introduction of defects allows selective gas permeation; efforts have been made to control the size of these defects for higher selectivity. Permeation of entities other than gases, such as ions, is of fundamental scientific interest because of its potential application in desalination, detection and purification.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
School of Chemistry & Chemical Engineering, Anhui University, Hefei, Anhui 230601, PR China.
Superatoms are stable clusters that mimic the chemical behavior of individual atoms in the periodic table. Many endeavors have been devoted to the design and characterization of various superatoms, while engineering superatoms to mimic the chemistry of chalcogens remains a challenge. In this paper, we present a new superchalcogen by evaluating a hollow tetrahedral AlO cluster with theoretical calculations.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Department of Chemistry, Saitama University, Saitama City, Saitama 338-8570, Japan.
Rate coefficients for ion-polar-molecule reactions between acetonitrile molecules (CHCN) and nitrogen molecular ions (N), which are of importance to the upper atmospheric chemistry of Saturn's moon Titan, were measured for the first time at low translational temperatures. In the experiments, the reaction between sympathetically cooled N ions embedded in laser-cooled Ca Coulomb crystals and velocity-selected acetonitrile molecules generated using a wavy Stark velocity filter was studied to determine the reaction rate coefficients. Capture rate coefficients calculated by the Su-Chesnavich approach and by the perturbed rotational state theory considering the rotational state distribution of CHCN were compared to the experimental rate coefficients.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!