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Insights at the molecular level into the formation of oxo-bridged trinuclear uranyl complexes. | LitMetric

Insights at the molecular level into the formation of oxo-bridged trinuclear uranyl complexes.

Chem Commun (Camb)

Chair of Inorganic Molecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany.

Published: February 2022

AI Article Synopsis

Article Abstract

Reaction of 1,3,4,6-tetra--acetyl--(2-hydroxy)-naphthylidene glucosamine (HL(Ac)) with uranyl acetate in ethanol leads to formation of dinuclear [(UO)(L)] (1). In a second step 1 is quantitatively transferred into the trinuclear oxo-bridged complex [(UO)(μ-O)(L)] (2) deprotonation and coordination of a water molecule. This transformation was followed by NMR and UV/Vis spectroscopy and it proved possible to selectively introduce O into the μ-bridge.

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Source
http://dx.doi.org/10.1039/d1cc06310cDOI Listing

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