Synthesis of a Biodegradable and Environmentally Friendly Shale Inhibitor Based on Chitosan-Grafted l-Arginine for Wellbore Stability and the Mechanism Study.

We synthesized a biodegradable and environmentally friendly shale inhibitor based on chitosan-grafted l-arginine (CA) for wellbore stability in shale formation. The structure of CA was characterized by Fourier-transform infrared spectroscopy. Linear swelling, shale hot-rolling recovery, shale inhibition durability, and sedimentation experiments were used to evaluate the inhibition properties of CA and compared with the commonly used inhibitors potassium chloride (KCl) and polyamines (HPA and SIAT). The results showed that the inhibition of CA was better than that of KCl, HPA, and SIAT and that it can have a shale hot-rolling recovery of more than 90% at 150 °C, which indicated that CA had higher temperature resistance and longer durability. More importantly, it can be biodegraded as exhibited by the biodegradibility experiment. The inhibition mechanism of CA was studied by particle size distribution, X-ray diffraction, scanning electron microscopy, zeta potential analysis, and contact angle test. The strong inhibition of CA can be attributed to its encapsulation of MMT and shale surfaces. The CA with strongly positively charge was firmly adsorbed on the surface of MMT and shale, which not only neutralized the negative charge of MMT, compressed the diffused electric double layer, but also increased the contact angle of MMT and shale surface which enhancing hydrophobicity of MMT and shale. The hydration swelling and dispersion of MMT and shale were further inhibited. In addition, compatibility experiments showed that CA was compatible with commonly used treatment agents. CA did not affect the rheology of water-based drilling fluids and can reduce fluid loss after aging.