This study evaluated the surface characteristics and bond strength of Y-TZP treated with Er:YAG laser at different focal distances. 120 Y-TZP blocks were divided into five groups (n=24), according to the surface treatment: no treatment (C-); sandblasting with silica-coated aluminum oxide particles (C+); and Er:YAG laser application at focal distances of 1mm (Er:YAG-1), 4mm (Er:YAG-4), and 7mm (Er:YAG-7). Surface characteristics were analyzed using Vickers microhardness, confocal laser microscope, scanning electron microscopy (SEM), and X-ray diffractometer (XRD). For the bond strength test, 100 Y-TZP blocks were subdivided into two subgroups (n=10), according to the resin cement used: with (MDP+) or without 10-methacryloyloxydecyl dihydrogen phosphate (MDP-). The Vickers microhardness and surface roughness were analyzed by one-way ANOVA and bond strength by two-way ANOVA and Tukey's test for both (α=0.05). Vickers microhardness differences were not observed between the groups (p>0.05); C+ showed higher surface roughness values. SEM images showed micromorphological differences between the groups. The XRD data detected tetragonal crystals for C- and, for the other groups, tetragonal and monoclinic peaks. For bond strength, no statistically difference significance were observed among the cements with or without MDP (p>0.05) but showed significant difference between the surface treatments (C+ > C- = Er:YAG1 > Er:YAG4 = Er:YAG7) (p<0.05). Suggested that the Er:YAG laser cannot replace conventional treatment with aluminum oxide particles and the presence of MDP in the resin cement had no influence on the bond strength.
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http://dx.doi.org/10.1590/0103-6440202104739 | DOI Listing |
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January 2025
Institute of Materials for Energy and Environment, College of Materials Science and Engineering, Qingdao University, Qingdao, 266071, P. R. China.
Construction of core-shell structured electrocatalysts with a thin noble metal shell is an effective strategy for lowering the usage of the noble metal and improving electrocatalytic properties because of the structure-induced geometric and electronic effects. Here, the synthesis of a novel core-shell structured nanocatalyst consisting of a thin amorphous Pd shell and a crystalline PdCu core and its significantly improved electrocatalytic properties for both formic acid oxidation and oxygen reduction reactions are shown. The electrocatalyst exhibits 4.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Laboratoire d'Energétique et des Transferts Thermique et Massique (LETTM), Faculté des Sciences de Tunis, Université de Tunis El Manar, Campus Universitaire El-Manar, El Manar, Tunis 2092, Tunisia.
The viability of using fibers as reinforcement material for developing lightweight sustainable non-structural construction materials in compliance with the valorization of local by-products has been investigated in this work. This study aims to investigate the effect of the chemical treatment of fibers on the mechanical and hygric properties of bio-sourced clay-sand- fiber composite. This lightweight specimen has been produced from a mixture of 60% natural clay and 40% sand by mass, as a matrix, and reinforced with different amounts of Juncus fibers.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
College of Civil Science and Engineering, Yangzhou University, Yangzhou 225100, China.
Polymers (Basel)
January 2025
State Key Laboratory of Chemical Safety, Qingdao 266000, China.
Polyurea (PUR) has been widely used as a protective coating in recent years. In order to complete the understanding of the relationship between PUR microstructure and its energy absorption capabilities, the mechanical and dynamic performance of PURs containing various macrodiol structural units were compared using material characterization techniques and molecular dynamic simulation. The results showed that the PUR polycarbonate diols formed as energy absorbing materials showed high tensile strength, high toughness, and excellent loss factor distribution based on the comparison of stress-strain tensile curves, glass transition temperatures, phase images, and dynamic storage loss modulus.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
College of Biological Engineering, Sichuan University of Science and Engineering, Yibin, Sichuan 644005, China. Electronic address:
Cellulose-based paper is inherently poor in hydrophobicity and mechanical strength, limiting its practical applications in daily life such as packaging materials, water-resistant labels, and disposable tableware. This study aimed to develop an effective and eco-friendly strategy to address these limitations by enhancing the hydrophobicity and mechanical properties of cellulose paper. To achieve this, an internal sizing agent was prepared by combining (3-glycidoxypropyl) trimethoxy (GPS) with natural rosin.
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