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Preparation of enantioenriched helical- and axial-chiral molecules by dynamic asymmetric induction. | LitMetric
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Preparation of enantioenriched helical- and axial-chiral molecules by dynamic asymmetric induction.

Yuuya Kawasaki Ryota Kamikubo Yuta Kumegawa Kouhei Ogawa Takeru Kashiwagi Yusuke Ano Kazunobu Igawa Katsuhiko Tomooka

Chem Commun (Camb)

Institute for Materials Chemistry and Engineering, and IRCCS, Kyushu University, Kasuga, Fukuoka 816-8580, Japan.

Published: February 2022

Dynamic asymmetric induction (DYASIN) of racemic dynamic chiral heterohelicenes afforded their highly enantioenriched forms (up to 96% ep) in quantitative yields. These heterohelicenes were readily converted into semi-static axial-chiral 1,1'-binaphthyl derivatives in a stereospecific manner.

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 Source
http://dx.doi.org/10.1039/d1cc05881aDOI Listing

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