(DippNacNac)Ga (DippNacNac = HC{C(Me)N(Dipp)}; Dipp = 2,6-iPrCH) was used as a trapping reagent for the unstable compounds BuSbH and MeBiH to yield (DippNacNac)GaH(SbHBu) (1) and {(DippNacNac)GaH(BiMe)} (2). Moreover, its reactions with a row of alkylated or arylated dichloro-bismuthenes resulted in either bridged species or the formation of a dibismuthane.
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