AI Article Synopsis
Article Abstract
Phonolite material has shown to be promising catalyst support for the deoxygenation of triglycerides. In this work, we continue with our previous research by synthesising and testing three acid-treated phonolite-supported Co-Mo, Ni-Mo and Ni-W catalysts for the hydrotreating of atmospheric gas oil and co-processing with rapeseed oil at industrial operating conditions (350-370 °C, WHSV 1-2 h, 5.5 MPa) in the continuous regime for more than 270 h. The phonolite-supported catalysts showed hydrotreating activity comparable with commercial catalysts, together with a complete conversion of triglycerides into n-alkanes. During co-processing, the Ni-promoted catalyst showed strong stability, with similar activity previous to the rapeseed oil addition. Our results enable us to evaluate the suitability of phonolite as catalyst support for the development of plausible alternatives to conventional hydrotreating catalysts for the co-processing of middle distillates with vegetable oils.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8746302 | PMC |
| http://dx.doi.org/10.3390/ma15010386 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Enhancing Catalytic Removal of Autoexhaust Soot Particles via the Modulation of Interfacial Oxygen Vacancies in Cu/CeO Catalysts.
Environ Sci Technol
January 2025
State Key Laboratory of Heavy Oil Processing, Key Laboratory of Optical Detection Technology for Oil and Gas, College of Science, China University of Petroleum, Beijing 102249, PR China.
The purification efficiency of autoexhaust carbon strongly depends on the heterogeneous interface structure between active metal and oxide, which can modulate the local electronic structure of defect sites to promote the activation of reactant molecules. Herein, the high-dispersion CuO clusters supported on the well-defined CeO nanorods were prepared using the complex deposition slow method. The formation of heteroatomic Cu-O-Ce interfacial structural units as active sites can capture electrons to achieve activation of the NO and O molecules.
View Article and Find Full Text PDFHO Mediated Photoreduction of Nitrates to Ammonia by Iron Filings under Ambient Conditions.
J Phys Chem Lett
January 2025
Department of Chemistry, Malaviya National Institute of Technology, Jaipur, Jaipur 302017, India.
Herein, a simple ambient conditioned sunlight promoted photochemical reduction reaction is demonstrated for the of nitrate (NO) conversion to ammonia (NH) with the maximum conversion yield of ∼16 mM using iron filings (f-Fe) in the presence of HO. Based on a radical scavenging study of reactive species and the characterization of catalyst f-Fe before and after the reaction, a plausible mechanism has been proposed for the ambient conditioned synthesis of NH. The results associated with the NH synthesis have been verified using the N isotopic labeled nitrate (NO), which supports the simpler viability of the reported procedure.
View Article and Find Full Text PDFNiFe-based arrays with manganese dioxide enhance chloride blocking for durable alkaline seawater oxidation.
J Colloid Interface Sci
January 2025
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014 Shandong, China; Center for High Altitude Medicine, West China Hospital, Sichuan University, Chengdu 610041 Sichuan, China. Electronic address:
Seawater splitting is increasingly recognized as a promising technique for hydrogen production, while the lack of good electrocatalysts and detrimental chlorine chemistry may hinder further development of this technology. Here, the interfacial engineering of manganese dioxide nanoparticles decorated on NiFe layered double hydroxide supported on nickel foam (MnO@NiFe LDH/NF) is reported, which works as a robust catalyst for alkaline seawater oxidation. Density functional theory calculations and experiment findings reveal that MnO@NiFe LDH/NF can selectively enrich OH and repel Cl in oxygen evolution reaction (OER).
View Article and Find Full Text PDFAssembly-foaming synthesis of hierarchically porous nitrogen-doped carbon supported single-atom iron catalysts for efficient oxygen reduction.
J Colloid Interface Sci
January 2025
Particle Engineering Laboratory (China Petroleum and Chemical Industry Federation), School of Chemical and Environmental Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 Jiangsu, PR China. Electronic address:
High-performance electrocatalysts are highly concerned in oxygen reduction reaction (ORR) related energy applications. However, facile synthesis of hierarchically porous structures with highly exposed active sites and improved mass transfer is challenging. Herein, we develop a novel assembly-foaming strategy for synthesizing hierarchically porous nitrogen-doped carbon supported single-atom iron catalysts.
View Article and Find Full Text PDFIntroduction: Addressing physician burnout is critical for healthcare systems. As electronic health record (EHR) workload and teamwork have been identified as major contributing factors to physician well-being, we aimed to mitigate burnout through EHR-based interventions and a compassion team practice (CTP), targeting EHR workload and team cohesion.
Methods: A modified stepped wedge-clustered randomized trial was conducted, involving specialties with heavy InBasket workloads.
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!