Currently, the production of one ton of ordinary Portland cement (OPC) releases considerable amounts of CO into the atmosphere. As the need and demand for this material grows exponentially, it has become a challenge to increase its production at a time when climate-related problems represent a major global concern. The two main CO contributors in this process are fossil fuel combustion to heat the rotary kiln and the chemical reaction associated with the calcination process, in the production of the clinker, the main component of OPC. The current paper presents a critical review of the existent alternative clinker technologies (ACTs) that are under an investigation trial phase or under restricted use for niche applications and that lead to reduced emissions of CO. Also, the possibility of transition of clinker production from traditional rotary kilns based on fuel combustion processes to electrification is discussed, since this may lead to the partial or even complete elimination of the CO combustion-related emissions, arising from the heating of the clinker kiln.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8746203 | PMC |
http://dx.doi.org/10.3390/ma15010209 | DOI Listing |
Materials (Basel)
December 2024
Facultad de Ingeniería Mecánica y Eléctrica, Universidad Autónoma de Nuevo León, Av. Pedro de Alba s/n, Ciudad Universitaria, San Nicolás de los Garza C.P. 66450, NL, Mexico.
An alternative approach to reducing the clinker factor, i.e., worldwide CO emissions resulting from the production of composite cement, is to replace these materials with supplementary aluminosilicate-based materials that promote the formation of alkali-activated cements, whose elevated temperature resistance, limited permeability, strong binding properties, excellent durability, high chemical corrosion resistance, confinement of toxic waste, and environmentally low impact have attracted a lot of attention in the cement industry.
View Article and Find Full Text PDFHeliyon
October 2024
Department of Earth Science, School of Physical and Mathematical Sciences, College of Basic and Applied Science, University of Ghana, P. O. Box LG 58, Legon, Ghana.
Faced with challenges like resource depletion and climate change, the cement industry needs sustainable solutions. This study explores the potential of geologically-delinaeated black shale from Apersua, Ghana, as a supplementary cementitious material (SCM) to reduce reliance on traditional methods. The researchers analysed the shale's chemical composition and mineralogy, then created laboratory cement formulations with varying black shale content.
View Article and Find Full Text PDFMaterials (Basel)
August 2024
School of Minerals Processing & Bioengineering, Central South University, Changsha 410083, China.
Concrete production is associated with extensive energy consumption and significant CO emissions. In addition, tremendous amounts of freshwater are used as a mixing agent. Urgency is increasing to develop sustainable cementitious materials and promote freshwater-saving strategies.
View Article and Find Full Text PDFMaterials (Basel)
June 2024
Faculty of Materials Engineering, Silesian University of Technology, Krasińskiego 8, 40-019 Katowice, Poland.
Calcium sulfoaluminate (CSA) cements are a promising alternative to Portland clinker, however, a thorough understanding of their properties is needed for their broader use in the industry. One of the topics that requires a good understanding is the effect of the w/c ratio on the properties of CSA cements. To this end, the aim of this paper was to provide research into the effects of a w/c ratio in the range of 0.
View Article and Find Full Text PDFChem Rev
June 2024
Physical Chemistry, Department of Chemistry, University of Konstanz, Universitätsstr. 10, 78457 Konstanz, Germany.
Understanding the crystallization of cement-binding phases, from basic units to macroscopic structures, can enhance cement performance, reduce clinker use, and lower CO emissions in the construction sector. This review examines the crystallization pathways of C-S-H (the main phase in PC cement) and other alternative binding phases, particularly as cement formulations evolve toward increasing SCMs and alternative binders as clinker replacements. We adopt a perspective, which recognizes the existence of critical intermediate steps between ions in solution and the final crystalline phases, such as solute ion associates, dense liquid phases, amorphous intermediates, and nanoparticles.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!