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Anti-inflammatory Dimeric Benzophenones from an Endophytic Pleosporales Species. | LitMetric
Eight new polyketides, including three dimeric benzophenones, named dipleosporones A-C (-), three benzophenones (-), one xanthone (), and one phenylbenzoate (), along with seven known polyketides (-) were isolated from the fungus Pleosporales sp. YY-4. The structures of the new compounds were established on the basis of spectroscopic methods, including high-resolution electrospray ionization mass spectrometry and one- and two-dimensional nuclear magnetic resonance. This is the first report of a benzophenone dimer connection via a C bridge from natural sources. An anti-inflammatory assay indicated that the dimeric benzophenones (-) inhibited lipopolysaccharide-induced NO production in RAW 264.7 cells, with half-maximal inhibitory concentration (IC) values ranging from 8.8 to 18.1 μM, being more potent than the positive control, dexamethasone (IC = 22.2 μM).
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