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Silver oxide(I) promoted Conia-ene/radical cyclization for a straightforward access to furan derivatives. | LitMetric
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Silver oxide(I) promoted Conia-ene/radical cyclization for a straightforward access to furan derivatives.

Bao Yu Selkti Mohamed Janick Ardisson Marie-Isabelle Lannou Geoffroy Sorin

Chem Commun (Camb)

Unité CNRS UMR 8038 Université de Paris, CNRS, CiTCoM, Faculté de Pharmacie, Sorbonne Paris Cité, 4 avenue de l'Observatoire, 75270 PARIS (France) 4 avenue de l'Observatoire, F-75006 Paris, France.

Published: January 2022

A novel access to fused furan cores using silver oxide(I) has been developed. Mechanistic investigations indicate the involvement of a Conia-ene reaction/radical cyclization for an expedient path to complex furan derivatives. The reaction is broad in scope with interesting atom economy and can also be conducted in a one-pot fashion from readily accessible α,β-unsaturated ketones.

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 Source
http://dx.doi.org/10.1039/d1cc06379kDOI Listing

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