We present the synthesis and catalytic properties of two novel telluroniobates {TeNb} and {TeNb}. {TeNb} is the first trimeric telluroniobate with the largest number of tellurium atoms in the Te-Nb system. Besides, both clusters exhibit excellent catalytic activity in the amidation reactions of anhydrides and amines, and cyclic imides and bi-amides can be controllably synthesized, which represents a breakthrough in the catalysis of polyoxoniobates.
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| http://dx.doi.org/10.1039/d1cc06781h | DOI Listing |
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