Further Advancement of Perovskite Single Crystals.

Halide perovskite (HP) single crystals (SCs) are garnering extensive attention as active materials to substitute polycrystalline counterparts in solar cells, photodiodes, and photodetectors, etc. Nevertheless, the large thickness and defect-rich surface results in severe carrier recombination and becomes the major bottleneck for augmented performance. In this perspective, we are looking forward to explaining in detail why the SCs hardly unleash their engrossing potential and introduce two parallel paths for further advancement. First is the modification of thick SCs by reducing the prepared thickness or surface passivation. Second is the large thickness that is conducive to the sufficient absorption of high-energy rays with strong penetrating ability and is beneficial to the thermoelectric effect due to the ultralow thermal conductivity of HPs. These applications provide a roundabout strategy to exploit freestanding SCs with a large thickness. Herein, direct modification and application of thick SCs are systematically introduced, expecting to give rise to the prosperity of HP SCs.