Hydrogen Production through Catalytic Water Splitting Using Liquid-Phase Plasma over Bismuth Ferrite Catalyst.

This study examined the H production characteristics from a decomposition reaction using liquid-phase plasma with a bismuth ferrite catalyst. The catalyst was prepared using a sol-gel reaction method. The physicochemical and optical properties of bismuth ferrite were analyzed. H production was carried out from a distilled water and aqueous methanol solution by direct irradiation via liquid-phase plasma. The catalyst absorbed visible-light over 610 nm. The measured bandgap of the bismuth ferrite was approximately 2.0 eV. The liquid-phase plasma emitted UV and visible-light simultaneously according to optical emission spectrometry. Bismuth ferrite induced a higher H production rate than the TiO photocatalyst because it responds to both UV and visible light generated from the liquid-phase plasma.