The non-Markovian dynamics of a charged particle confined in the harmonic oscillator and linearly coupled to a neutral bosonic heat bath is investigated in the external uniform magnetic field. The analytical expressions are derived for the time-dependent and asymptotic orbital angular momenta. The transition from non-Markovian dynamics to Markovian dynamics and the transition from a confined charge particle to a free charge particle are considered. The orbital diamagnetism of graphene in a dissipative environment and an external uniform magnetic field is studied and compared with existing experimental data. The results are presented for the electric conductivity and resonance behavior of the mass magnetization in graphene.
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http://dx.doi.org/10.1103/PhysRevE.104.054120 | DOI Listing |
J Am Chem Soc
December 2024
Chemistry Research Laboratory, Department of Chemistry, Oxford OX1 3TA, U.K.
High-valent nickel species are implicated as intermediates in industrially relevant chemical transformations and in the catalytic cycles of metalloenzymes. Although a small number of tetravalent NiX complexes have been crystallographically characterized, higher nickel valence states have not been identified. Here we report a stable, crystalline NiX complex, Ni(BeCp) (; cyclopentadienyl anion (Cp)), formed by the insertion of zerovalent nickel into three Be-Be bonds.
View Article and Find Full Text PDFChem Sci
December 2024
Nikolayev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences 630090 Novosibirsk Russia
Radical lanthanide complexes are appealing platforms to investigate the possibility to engineer relevant magnetic couplings between the two magnetic centers by exploiting the strongly donating magnetic orbitals of the radical. In this paper, we report a spectroscopic and magnetic study on [LnRad(NO)], where Ln = Eu or Lu and Rad is the tridentate tripodal nitroxyl radical 4,4-dimethyl-2,2-bis(pyridin-2-yl)-1,3-oxazolidine-3-oxyl. A thorough magnetic investigation by Electron Paramagnetic Resonance (EPR) spectroscopy and magnetometry, fully supported by calculations, allowed us to unravel an unprecedentedly large antiferromagnetic coupling between the Eu and the radical ( = +19.
View Article and Find Full Text PDFInorg Chem
November 2024
Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford, OX1 3QR, United Kingdom.
Reaction between SrMnIrO and CaH or LiH yields the iridium-containing oxyhydride phases SrMnIrOH or SrMnIrOH, respectively. Analysis of Mn K-edge XANES data indicate the presence of Ir centers in these oxyhydride phases, whose low-spin d configuration is consistent with the "covalent stabilization" of the metastable oxyhydride phases, as seen previously in analogous ruthenium and rhodium containing materials. Neutron powder diffraction data indicate the hydride ions are located exclusively within the "equatorial" anion sites of SrMnIrOH.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
October 2024
Department of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan, 48824, USA.
For the first time, the capture of the planar antiaromatic parent benzene dianion in between two trivalent rare earth (RE) metal cations (RE), each stabilized by two guanidinate ligands, is reported. The synthesized inverse-sandwich complexes [{(MeSi)NC(NPr)}RE](μ-η : η-CH), (RE=Y (1), Dy (2), and Er (3)) were crystallized from aprotic solvents and feature a remarkably planar parent benzene dianion, previously not encountered for any metal ion prone to low or absent covalency. The -2 charge localization at the benzene ligand was deduced from the results obtained by single-crystal X-ray diffraction analyses, spectroscopy, magnetometry, and Density Functional Theory (DFT) calculations.
View Article and Find Full Text PDFDalton Trans
October 2024
Department of Chemistry, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192, Japan.
The symmetry of one of the simplest hexamonodentate complexes, [M(HO)] (M = Fe, Co, Ni, and Zn), was controlled by tuning interactions in the second coordination sphere. Highly symmetric Ti-Mo or Zr-Mo cluster cations acted as symmetry templates, imposing a crystallographic trigonal coordination geometry in the hexamonodentate complexes through intermolecular hydrogen-bonding interactions. Magnetic measurements revealed that the ideal trigonal symmetry results in weak spin-orbit coupling for high-spin Fe complexes, despite the T-term ground state in the octahedral geometry.
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