The hybrid system of constructed wetland and microbial fuel cell (CW-MFC) used as a biosensor is becoming a new research focus with the advantage of resisting the shock loading and enriching more electricigens. In this study, a structural parameter S integrating the size, the position and the spacing of the anode and the cathode was proposed. And the electrogenesis and biosensing performances of the vertical flow CW-MFC biosensors were evaluated at different S values. The results showed that all the three biosensors could achieve good monitoring for COD (R > 0.97). And the coulombic yield was more suitable for the response signal than output voltage. But different biosensing properties including detection signal, detection range, detection time, correlation fitting degree and sensitivity were also displayed. Further, in order to optimize the biosensing performance, the coulombic yield in stable voltage stage (Qs) was proposed which can shorten the detection time by 70% at most. On the anodes, abundant nitrogen-transforming bacteria (NTB) were enriched as well as electrochemically active bacteria (EAB). The competition of NTB for substrates and electrons with EAB disturbed the output voltage signal but not affect the stability of coulombic yield signal. Moreover, the significant linear correlation between the S values and the ratios of EAB to NTB colonized both on anodes and on cathodes indicated the differences of the electricity generation and biosensing performance at the different structural parameters.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1016/j.watres.2021.117957 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Preparation and photoelectric properties of Si:B nanowires with thermal evaporation method.
PLoS One
January 2025
College of Physics and Electronic Engineering, Hainan Normal University, HaiKou, China.
We have successfully prepared a significant number of nanowires from non-toxic silicon sources. Compared to the SiO silicon source used in most other articles, our preparation method is much safer. It provides a simple and harmless new preparation method for the preparation of silicon nanowires.
View Article and Find Full Text PDFLow-Impedance Hybrid Carbon Structures on SiO: A Sequential Gas-Phase Coating Approach.
Small Methods
January 2025
BCMaterials, Basque Centre for Materials, Applications and Nanostructures; UPV/EHU Science Park, Leioa, 48940, Spain.
Carbon coating on SiO surface is crucial for enhancing initial Coulombic efficiency (ICE) and cycling performance in batteries, while also buffering volume expansion. Despite its market prevalence, the effects of the carbon layer's quality and structure on the electrochemical properties of SiO remain underexplored. This study compares carbon layers produced via gas-phase and solid-phase coating methods, introducing an innovative technique that sequentially uses two gases to develop a low-impedance hybrid carbon structure.
View Article and Find Full Text PDFSynthesis of Arsenocholine-Type Polycation Brush and Its Hydration Structure in Aqueous Solution.
Langmuir
January 2025
School of Advanced Engineering, Kogakuin University, Tokyo 192-0015, Japan.
Arsenocholine-containing methacrylate (MTAsB) inspired by marine organisms was synthesized by the reaction of 2-bromoethyl methacrylate and trimethylarsine to investigate its polymerization behavior and the fundamental properties of the resulting polymer. Controlled radical polymerization of MTAsB proceeded in the presence of a copper catalyst and imidazolium chloride at 60 °C for 8 h to give a water-soluble polycation with a 94% yield. The smaller amount of nonfreezing water and intermediate water of poly(MTAsB) was observed compared with that of the ammonium-containing polycations.
View Article and Find Full Text PDFEffect of pre-treatment conditions on the electrochemical performance of hard carbon derived from bio-waste.
RSC Adv
January 2025
Department of Chemical and Materials Engineering, School of Engineering and Digital Sciences, Nazarbayev University Astana Kazakhstan
Sodium-ion batteries (SIBs) offer several advantages over traditional lithium-ion batteries, including a more uniform sodium distribution, lower-cost materials, and safer transportation options. A promising development in SIBs is the use of hard carbons as anode materials due to their low insertion voltage and larger interlayer spacing, which improve sodium-ion insertion. Traditionally, hard carbons are made from costly carbon sources, but recent advancements have focussed on using abundant bio-waste, like coffee grounds.
View Article and Find Full Text PDFB(MIDA)-directed site-selective intermolecular halofluoroalkylation of alkenes: synthesis of diversely functionalized building blocks.
Chem Sci
January 2025
State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences Shanghai 201203 China
α-Halo borides are generally constructed Matteson homologation, and the synthesis of both fluorinated and functionalized ambiphilic boronates is challenging and has received inadequate attention. Herein, we describe the -methyliminodiacetyl boronate [B(MIDA)]-directed halogenation of alkenes a complementary sequence involving fluoroalkyl radical addition followed by guided radical-to-metal oxidative addition and C-X reductive elimination. The alkali cation and functional groups in B(MIDA) enable coulombic interaction and weak attraction with halogens, which could weaken the Pd-X bond and assist in C-X bond formation and is verified by DFT calculations.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!