The patterned metal halide perovskites exhibit novel photophysical properties and high performance in photonic applications. Here, we show that a UV continuous wave laser can induce crystallization of individual and patterned CsPbBr quantum dots (QDs) inside the CsPbBr microplatelets. The microplatelet acts as a natural Fabry-Perot cavity and causes the high-Purcell-effect-enhanced (by 287 times) cavity mode spontaneous emission of the embedded CsPbBr QDs. The luminescence exhibits a superlinear emission intensity-excitation intensity relation () ∝ , and the exponent is much bigger than that of the free-space exciton spontaneous emission, suggesting arising of stimulated emission at higher photon concentrations. These laser-driven crystallized and patterned cavity mode luminescent perovskite QDs in a waterproof wider-bandgap perovskite microcavity act as an ideal platform for studying the cavity quantum electrodynamics phenomena and for applications in information storage and encryption, anticounterfeiting, and low-threshold lasers.

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http://dx.doi.org/10.1021/acs.nanolett.1c04025DOI Listing

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