Modulation of the Host-Guest-Guest Interactions in a Metal-Organic Framework for Multiple Anticounterfeiting Applications.

Inorg Chem

Key Laboratory of Advanced Materials of Tropical Island Resources, Ministry of Education, College of Science, Hainan University, Haikou 570228, China.

Published: January 2022

Developing fluorescent materials with multiple and tunable emissions under different conditions is necessary to meet the growing demand for optical anticounterfeiting technology. Different modes of fluorescence emission can be obtained by loading multiple fluorescent components into metal-organic frameworks (MOFs) and modulating the interaction among them for multiple anticounterfeiting purposes. Herein, a Cd-based MOF () was constructed as a host to encapsulate both lanthanide ions and carbon quantum dots. Multiple fluorescence emissions can be achieved by modulation of host-guest and guest-guest interaction, which holds promise for multiple anticounterfeiting applications. This work opens the opportunity to construct the hybrid MOF-based materials with controlled fluorescence properties for emerging anticounterfeiting applications in various fields.

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http://dx.doi.org/10.1021/acs.inorgchem.1c03139DOI Listing

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