The production of new cost-effective biocompatible sorbent sustainable materials, with natural origins, able to remove heavy metals from water resources is nowadays highly desirable in order to reduce pollution and increase clean water availability. In this context, self-assembled protein materials with amyloid structures seem to have a great potential as natural platform for a broader development of highly-tunable structures. In this work we show how protein particulates, a generic form of protein aggregates, with spherical micro sized shape can be used as adsorbents of Pb ions from aqueous solution. The effect of pH, ionic medium, ionic strength and temperature of the metal ion solution on the adsorption ability and affinity has been evaluated revealing the complexity of adsorption mechanisms which are the result of the balance of specific interactions with functional groups in protein structure and not specific ones common to all polypeptide chains, and possibly related to amyloid state and to modification of particulates hydration layer.
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http://dx.doi.org/10.1016/j.jcis.2021.11.184 | DOI Listing |
Environ Sci Pollut Res Int
December 2024
Department of Chemistry, Faculty of Science, Ain Shams University, Abbasia, Cairo, 11566, Egypt.
A magnetic nanocomposite adsorbent, comprised of macroporous iron oxide/manganese oxide (α-FeO/MnO), is prepared, characterized, and used for lead(II) removal from both industrial wastewater and leachate of electronic waste. The synergistic interaction between iron oxide and manganese oxide significantly enhances the adsorption performance. The surface characteristics and structural composition of the nanocomposite are examined using high-resolution transmission microscopy, X-ray spectroscopy, and Brunauer-Emmett-Teller methods.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Chemistry Department, Faculty of Science, Damanhour University, Damanhour, Egypt.
Lead (Pb(II)) contamination poses a significant threat to human health and the environment. This study investigates a new approach for Pb(II) removal from polluted water using copper terephthalic acid metal-organic framework/gum Arabic/potassium carrageenan (MGC) composite beads. We synthesized copper terephthalic acid MOF, potassium carrageenan beads, and MGC composite beads to evaluate their adsorption potential.
View Article and Find Full Text PDFAnal Bioanal Chem
December 2024
Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, ON, K1S 5B6, Canada.
Sci Rep
October 2024
Department of Chemistry, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran.
This study introduces a novel ion-imprinted polymer for the ultrasensitive detection of mercury(II) in water. The ion-imprinted polymer was synthesized via a simple bulk polymerization process using methacrylic acid as the functional monomer, ethylene glycol dimethacrylate as the cross-linker, morpholine-4-carbodithioic acid phenyl ester as the chelating agent, and ammonium persulfate as the initiator. The electrochemical mercury(II) sensing capability of the ion-imprinted polymer was studied via the modification of a cost-effective carbon paste electrode.
View Article and Find Full Text PDFChem Commun (Camb)
October 2024
Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY-14853, USA.
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