Nowadays, carbon-based nano-structured materials are widely preferred for composite coating as anti-corrosive reinforcement mainly due to its enhanced physical, chemical and mechanical properties. Herein we develop highly efficient Graphitic carbon nitride-Silica-Titania (gCN/SiO/TiO) ternary nanocomposite are synthesized and it is used as a nanofillers in the corrosive protection layer on the proposed metal specimen (i.e., mild steel specimen) in an aggressive chloride environment. Size, structural and morphological analysis were analysed for the confirmation of presence of particles. gCN is currently earning quite drastic attention, owing to its affordable cost compared to carbon nanotubes and other carbon-based materials, when gCN incorporated with SiO and TiO, the composite matrix greatly improves the mechanical strength of the coating mixture. XRD, XPS, EDS analysis projects excellent formation and presence of the ternary nanocomposites. The particles are well-dispersed in epoxy and organic resin and deposited on the mildsteel panels and it is examined using various surface and structural characterization techniques. The obtained results are very encouraging and the ternary composite coatings can be recommended for real world applications.
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http://dx.doi.org/10.1016/j.chemosphere.2021.133332 | DOI Listing |
Membranes (Basel)
December 2024
Unit of Chemical Technologies, Technology Centre of Catalonia, Eurecat, 43007 Tarragona, Spain.
The urgent need for sustainable, low-emission energy solutions has positioned proton exchange membrane fuel cells (PEMFCs) as a promising technology in clean energy conversion. Polysulfone (PSF) membranes with incorporated ionic liquid (IL) and hydrophobic polydimethylsiloxane-functionalized silica (SiO-PDMS) were developed and characterized for their potential application in PEMFCs. Using a phase inversion method, membranes with various combinations of PSFs, SiO-PDMS, and 1-butyl-3-methylimidazolium triflate (BMI.
View Article and Find Full Text PDFBiosensors (Basel)
November 2024
Department of BioNano Technology, Gachon University, 1342 Seongnamdae-ro, Sujeong-gu, Seongnam 13120, Republic of Korea.
Choline is an important molecule in monitoring food safety and infant nutrition. Here, we report Ce nanogels synthesized by atom transfer radical polymerization (ATRP) employing Ce-coordinated acryloyl-lysine polymer brushes (Ce@SiO NGs) as highly efficient cascade nanozymes for colorimetric detection of choline. The synthesized Ce@SiO NGs demonstrated remarkable peroxidase-like activity with a porous exterior, which are essential to entrap choline oxidase (COx) to yield COx@Ce@SiO NGs and construct a cascade reaction system to detect choline.
View Article and Find Full Text PDFGels
December 2024
School of Resource and Safety Engineering, Central South University, Changsha 410083, China.
This research enhances the thermal safety of hydrophobic silica aerogel (HSA) by integrating layered double oxides (LDOs). XRD and FTIR confirm that the introduction of LDOs does not affect the formation of SA. The LDO/SA composites demonstrate a low density (0.
View Article and Find Full Text PDFChemosphere
December 2024
Division of Advanced Nuclear Engineering, POSTECH, 77, Cheongam-ro, Nam-gu, Pohang, Korea; Division of Environmental Science & Engineering, POSTECH, 77, Cheongam-ro, Nam-gu, Pohang, Korea. Electronic address:
Bentonite is regarded as an adequate buffer material in deep geological repositories and its swelling properties serve to prevent the penetration of groundwater into the repository and to minimize the release of radionuclides. However, bentonite is rarely effective in removing anionic radionuclides due to its permanent negative surface charge. The aim of this study was to enhance the anion removal ability of bentonite by incorporating layered double hydroxides (LDH) with a high anion exchange capacity.
View Article and Find Full Text PDFACS Omega
December 2024
Department of Petroleum Engineering, King Fahd University of Petroleum & Minerals, Dhahran 34464, Saudi Arabia.
In chemical-enhanced oil recovery (cEOR), surfactants are widely used but face significant stability challenges in high-salinity brine, where they often degrade or precipitate. Existing methods, such as adding cosurfactants, offer limited compatibility with anionic surfactants and raise economic concerns, creating a need for more robust solutions. This study introduces a novel approach to enhance the stability of anionic surfactants in extreme salinity conditions by incorporating silicon dioxide (SiO) nanoparticles (NPs).
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