Low-filled suspensions of α-chitin nanorods for electrorheological applications.

Highly anisometric α-chitin nanoparticles isolated by TEMPO-oxidation were investigated as filler for electrorheological fluids. The dimensions of rod-like particles were determined by AFM and cryo-TEM methods. The rheological behavior of α-chitin nanoparticles in polydimethylsiloxane changes from viscous to elastic under electric field. The yield stress reaches about 220 Pa at 7 kV/mm for 1.0 wt% fluid. Despite the nanosize of particles, the suspensions sedimentation ratio was found to be low (~23%). The electrorheological behavior of the fluids was discussed in terms of the Mason numbers. The stability of fluids response under switching electric field was shown. The activation energy of polarization processes in suspensions was calculated as 58 ± 2 and 64 ± 1 kJ/mol for 0.5 and 1.0 wt% filler content from the impedance spectra. The high aspect ratio (~70) and dielectric permittivity result in high electrorheological activity of α-chitin suspensions at extremely low concentrations (≤1.0 wt%).