Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes.

Chem Commun (Camb)

State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, P. R. China.

Published: December 2021

The Co-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes were realized by a ligand-controlled strategy. The remote hydroboration with dcype provided borylethers, while xantphos favored the formation of silyl enol ethers.

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Source
http://dx.doi.org/10.1039/d1cc05964eDOI Listing

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