As artificial marble is abundant and widely used in residential and commercial fields, the resource utilization of artificial marble wastes (AMWs) has become extremely important in order to protect the environment. In this paper, polybutylene terephthalate/artificial marble wastes (PBT/AMWs) composites were prepared by melt blending to maximize resource utilization and increase PBT performance. The research results showed that the filling of AMWs was beneficial to the improvement of PBT-related performance. X-ray diffraction analysis results indicated that after filling AMWs into the PBT matrix, the crystal structure of PBT was not changed. Heat deflection temperature (HDT) analysis results indicated that the HDT of PBT composites with 20 wt% AMWs reached 66.68 °C, which was 9.12 °C higher than that of neat PBT. Differential scanning calorimetry analysis results showed that heterogeneous nucleation could be well achieved when the filling content was 15 wt%; impact and scanning electron microscope analysis results showed that due to the partial core-shell structure of the AMWs, the impact strength of PBT was significantly improved after filling. When the filling amount was 20 wt%, the impact strength of the PBT composites reached 23.20 kJ/m, which was 17.94 kJ/m higher than that of neat PBT. This research will not only provide new insights into the efficient and high-value utilization of AMWs, but also provide a good reference for improved applications of other polymers.
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http://dx.doi.org/10.3390/polym13234242 | DOI Listing |
Artificial bone, primarily composed of calcium carbonate, demonstrates a higher resorption rate than calcium phosphate-based counterparts, suggesting potential for early bone replacement. Animal experiments using porous calcium carbonate ceramics have demonstrated bone formation superior to commercially available artificial bone after short-term implantation. Long-term implantation has yielded suboptimal results owing to resorption of both newly formed bone and implantation material.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2024
School of Environmental Science and Engineering and The Key Laboratory of Municipal Solid Waste Recycling Technology and Management of Shenzhen City, Southern University of Science and Technology, Shenzhen, 518055, P. R. China.
Two anti-dissolution mechanisms of aragonite in acidified artificial seawater were investigated by monitoring the dissolution process in the presence of organic and inorganic additives. Among them, the carboxyl functional group (RCOO) in PAA bonds with Ca and bicarbonate, while strong protonation of silicates directly binds to hydrogen ions from bicarbonate. These interactions ultimately form stable polymer-rich amorphous calcium carbonate and dense silica layers on the surface of aragonite, effectively inhibiting further dissolution under dissolved CO.
View Article and Find Full Text PDFPLoS One
November 2024
Faculty of Agriculture, Department of Soil Science and Engineering, Shiraz University, Shiraz, IR Iran.
Characterization of near (field) saturated hydraulic conductivity (Kfs) of the soil environment is among the crucial components of hydrological modeling frameworks. Since the associated laboratory/field experiments are time-consuming and labor-intensive, pedotransfer functions (PTFs) that rely on statistical predictors are usually integrated with the existing measurements to predict Kfs in other areas of the field. In this study some of the most appropriate machine learning approaches, including variants of artificial neural networks (ANNs) were used for predicting Kfs by some easily measurable soil attributes.
View Article and Find Full Text PDFSci Rep
November 2024
Centre for Artificial Intelligence Research and Optimisation (AIRO), Torrens University Australia, Brisbane, Australia.
A key goal of environmental policies and circular economy strategies in the construction sector is to convert demolition and industrial wastes into reusable materials. As an industrial by-product, Waste marble (WM), has the potential to replace cement and fine aggregate in concrete which helps with saving natural resources and reducing environmental harm. While many studies have so far investigated the effect of WM on compressive strength (CS), it is undeniable that conducting experimental activities requires time, money, and re-testing with changing materials and conditions.
View Article and Find Full Text PDFMaterials (Basel)
October 2024
Faculty of Technology Novi Sad, University of Novi Sad, Bulevar Cara Lazara 1, 21000 Novi Sad, Serbia.
Using a Taguchi experimental design, this research focuses on utilizing indigenous bacteria from the Danube River to enhance the self-healing capabilities and structural integrity of cementitious materials. and were used as individual bacterium or in co-culture, with a concentration of 8 logs CFU, while the humidity variation involved testing wet and wet-dry conditions. Additionally, artificial neural network (ANN) modeling of the compressive strength of cement samples results in improvements in compressive strength, particularly under wet-dry conditions.
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