Crystal structure and Hirshfeld surface analysis of bis-[(eth-oxy-methane-thio-yl)sulfanido](,,','-tetra-methyl-ethane-1,2-di-amine)-mercury(II).

Acta Crystallogr E Crystallogr Commun

Department of Computer and Electronic Engineering Technology, Sanaa Community College, Sanaa, Yemen.

Published: November 2021

The title four-coordinate mononuclear complex, [Hg(CHOS)(CHN)] or [Hg(CHOS)(tmeda)] (tmeda: ,,','-tetra-methyl-ethane-1,2-di-amine), has a distorted tetra-hedral geometry. The Hg ion is coordinated to two N atoms of the ,,','-tetra-methyl-ethylenedi-amine ligand and two S atoms from two ethylxanthate xanthate ligands. In the crystal, mol-ecules are linked by weak C-H⋯S hydrogen bonds, forming a two-dimensional supra-molecular architecture in the plane. The most important contributions for the crystal packing are from H⋯H (59.3%), S⋯H (27.4%) and O⋯H (7.5%) inter-actions.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8587978PMC
http://dx.doi.org/10.1107/S2056989021010549DOI Listing

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