The title four-coordinate mononuclear complex, [Hg(CHOS)(CHN)] or [Hg(CHOS)(tmeda)] (tmeda: ,,','-tetra-methyl-ethane-1,2-di-amine), has a distorted tetra-hedral geometry. The Hg ion is coordinated to two N atoms of the ,,','-tetra-methyl-ethylenedi-amine ligand and two S atoms from two ethylxanthate xanthate ligands. In the crystal, mol-ecules are linked by weak C-H⋯S hydrogen bonds, forming a two-dimensional supra-molecular architecture in the plane. The most important contributions for the crystal packing are from H⋯H (59.3%), S⋯H (27.4%) and O⋯H (7.5%) inter-actions.
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http://dx.doi.org/10.1107/S2056989021010549 | DOI Listing |
Chem Asian J
January 2025
Kanagawa University, Department of Chemistry, JAPAN.
Thermoelectric properties of undoped crystals of dibenzo[g,p]chrysene (DBC), deuterated DBC (DBC-d16), and 2,10-dimethyl-DBC (DBC-Me2) have been studied to obtain some insights into the relationship between the structural parameters of materials and the giant Seebeck effect. X-ray crystallography showed one-dimensional columnar packing with the interlayer distances (d) for DBC-d16, DBC, and DBC-Me2 were 3.78 Å, 3.
View Article and Find Full Text PDFInorg Chem
January 2025
School of Physics and Materials Science, Changji University, Changji 831100, People's Republic of China.
Finding novel efficient nonlinear optical materials with large second-order nonlinearity for the UV spectral range remains a formidable challenge, especially for silicate systems. Using a high-temperature solid reaction in a tight vacuum environment, two ultraviolet nonlinear optical materials with a moderate second harmonic generation (SHG) response have been created: PbSiOC and PbCaSiO. The SHG values they computed are roughly 2.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Jinan University, State Key Laboratory of Bioactive Molecules and Druggability Assessment, CHINA.
Secupyritines A‒C are unique polycyclic Securinega alkaloids isolated from medicinal plant Flueggea suffruticosa. They feature a distinctive 6/6/6/5/6 fused pentacyclic ring system with a highly strained 2-oxa-6-aza[4.4.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China.
Uranium (U), a high-performing, low-emission energy source, is driving sustainable economic growth. Herein, we synthesized two crystalline phases (HPOC-α and β) by an unreported amidoxime organic cage used for uranium capture. The revealed crystal structures and uranium adsorption test showed that accessible functional groups were essential to uranyl ions sorption.
View Article and Find Full Text PDFFEBS J
January 2025
Institute of Bioorganic Chemistry, Polish Academy of Sciences, Poznan, Poland.
Rhizobium etli is a nitrogen-fixing bacterium that encodes two l-asparaginases. The structure of the inducible R. etli asparaginase ReAV has been recently determined to reveal a protein with no similarity to known enzymes with l-asparaginase activity, but showing a curious resemblance to glutaminases and β-lactamases.
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