The study highlights the potential of Vetiveria Zizanioides derived biochar for heavy metal removal in multicomponent systems. Biochar efficiency varies with pH, metal ion concentration and residence time. Maximum removal efficiency was found to be 66.34, 67.23, 46.54, 69.92, 68.23 and 63.34% for Arsenic, Copper, Nickel, Cadmium, Lead and Chromium at 90 min respectively. Ternary system revealed that Copper ions have inhibitory effect on Lead ions and have lower adsorption capacity than binary system. Multicomponent isotherm model was used to analyse simultaneous adsorption of metal ions and shows a good fit with modified Langmuir model for binary and ternary systems. Fixed-bed column was tested for scale-up feasibility and maximum adsorption capacity of 139, 130, and 123 mg/g for Lead, Copper, and Nickel ions were obtained at 1.5 L/h and a bed height of 12 cm. In fixed bed column, multicomponent sequence provides more protection against premature exhaustion of biochar.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1016/j.biortech.2021.126475 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Microalgae-based bioremediation of refractory pollutants: an approach towards environmental sustainability.
Microb Cell Fact
January 2025
Botany Department, Faculty of Science, Tanta University, Tanta, 31527, Egypt.
Extensive anthropogenic activity has led to the accumulation of organic and inorganic contaminants in diverse ecosystems, which presents significant challenges for the environment and its inhabitants. Utilizing microalgae as a bioremediation tool can present a potential solution to these challenges. Microalgae have gained significant attention as a promising biotechnological solution for detoxifying environmental pollutants.
View Article and Find Full Text PDFWorkflow-driven catalytic modulation from single-atom catalysts to Au-alloy clusters on graphene.
Sci Rep
January 2025
Department of Chemistry, Federal University of Paraná, Curitiba, 81531-980, Brazil.
Gold-based (Au) nanostructures are efficient catalysts for CO oxidation, hydrogen evolution (HER), and oxygen evolution (OER) reactions, but stabilizing them on graphene (Gr) is challenging due to weak affinity from delocalized [Formula: see text] carbon orbitals. This study investigates forming metal alloys to enhance stability and catalytic performance of Au-based nanocatalysts. Using ab initio density functional theory, we characterize [Formula: see text] sub-nanoclusters (M = Ni, Pd, Pt, Cu, and Ag) with atomicities [Formula: see text], both in gas-phase and supported on Gr.
View Article and Find Full Text PDFAn Adsorbent for Efficient and Rapid Gold Recovery from Solution: Adsorption Properties and Mechanisms.
Langmuir
January 2025
College of Optoelectronic Materials and Technology, Jianghan University, Wuhan, Hubei 430056, People's Republic of China.
Adsorption is an efficient and highly selective method for gold recovery. Introducing rich N/S organic groups to combine with metal-organic frameworks (MOFs) as adsorbents is regarded as a practical and efficient approach to enhance gold recovery. Herein, a MOF (zirconium isothiocyanatobenzenedicarboxylate MOF, UiO-66-NCS) was designed to combine with amidinothiourea (AT) to form UiO-66-AT (zirconium amidothiourea-benzenedicarboxylate MOF) for efficient and rapid adsorption.
View Article and Find Full Text PDFMulti-effect synergistic induction of unsaturated MnO on sandy sediment for enhanced manganese adsorption and byproduct resource recovery in solar evaporation.
J Hazard Mater
January 2025
School of Ecology and Environment, Zhengzhou University, 100 Kexue Avenue, Zhengzhou 450001, PR China; Henan International Joint Laboratory of Water Cycle Simulation and Environmental Protection, Zhengzhou 450001, PR China. Electronic address:
The efficient removal of Mn(II) from wastewater is crucial for safeguarding water quality, yet existing adsorbents face significant challenges, including high costs, poor resistance to ionic interference, and scalability limitations. This study addresses these challenges by utilizing abundant natural sandy sediment (SS) as a substrate to load unsaturated MnO via in-situ oxidation, creating a novel adsorbent (MOSS). MOSS exhibits a remarkable Mn(II) adsorption capacity of 1.
View Article and Find Full Text PDFHigh-entropy layered double hydroxides tailor Pt electron state for promoting acidic hydrogen evolution reaction.
J Colloid Interface Sci
January 2025
Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou, Jiangsu Province 213164, China. Electronic address:
Despite the advancement of the Pt-catalyzed hydrogen evolution reaction (HER) through oxophilic metal-hydroxide surface hybridization, its stability in acidic solutions remains unsatisfactory. This is primarily due to excessive aggregation of active hydrogen, which hinders subsequent hydrogen desorption, coupled with the poor operational stability of metal hydroxides. In this study, we have designed Pt nanoparticles-modified NiFeCoCuCr high-entropy layered double hydroxides (Pt/HE-LDH) that exhibit exceptional catalytic activity toward HER in acidic electrolytes.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!