In this study, the adsorption characteristics of marine dissolved organic matters (MDOMs) on the solid-liquid interface in the coastal waters was investigated. The results showed that the organic macromolecules with adsorption ability in MDOMs are not rigid molecules. However, the macromolecules have viscoelasticity properties. At different dilution ratios, the MDOMs adsorption process includes rapid (0-200 s) and slow adsorption (200 s later) periods. MDOMs adsorption in the solid-liquid interface is a dynamic process in which adsorption and hydration occur simultaneously. MDOMs concentration is an important driving force for adsorption. The three macromolecules of acid polysaccharides, protein-like, and polycarboxylate-type humic acids in MDOMs are rich in functional groups and they have the ability to absorb to solid surface. Acidic polysaccharides exhibit a sustained adsorption ability, while the adsorption of other macromolecules occurred only in the initial rapid adsorption period. In addition, the acid polysaccharides show weak thixotropy during the adsorption process. It would cause the stretching of macromolecular structure of the adsorption layer, enhancing the hydration of the adsorption layer. The study shows the adsorption process of MDOMs at the solid-liquid interface and the structural characteristics of the adsorption layer. It can provide helpful information for the inhibition and removal of MDOMs pollution during the actual development of marine resources.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1016/j.chemosphere.2021.133140 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Investigation the CMP process of 6 H-SiC in HO solution with ReaxFF molecular dynamics simulation.
Sci Rep
January 2025
College of Mechanical Engineering, Zhejiang University of Technology, No.18, Chaowang Road, Hangzhou, 310014, Zhejiang Province, China.
To observe the chemical mechanical polishing (CMP) process at the atomic scale, reactive force field molecular dynamics (ReaxFF-MD) was employed to simulate the polishing of 6 H-SiC under three conditions: dry, pure water, and HO solution. This study examined the reactants on the surface of 6 H-SiC during the reaction in the HO solution, along with the dissociation and adsorption processes of HO and water molecules. The mechanisms for atom removal during the CMP process were elucidated.
View Article and Find Full Text PDFStress-induced self-assembly of hierarchically twisted stripe arrays.
Sci Bull (Beijing)
December 2024
Department of Chemistry, Laboratory of Advance Materials, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, and iChEM, Fudan University, Shanghai 200433, China. Electronic address:
Hierarchical organization is prevalent in nature, yet the artificial construction of hierarchical materials featuring asymmetric structures remains a big challenge. Herein, we report a stress-induced self-assembly strategy for the synthesis of hierarchically twisted stripe arrays (HTSAs) with mesoporous structures. A soft and thin mesostructured film assembled by micelles and TiO oligomers is the prerequisite.
View Article and Find Full Text PDFCovalently crosslinked carboxymethyl chitosan beads containing SiO and ionic polymer for efficient adsorptive removal of methylene blue.
Int J Biol Macromol
January 2025
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, PR China. Electronic address:
The carboxymethyl chitosan (CMCS)-based porous beads are still criticized for their limited number of binding sites, which impairs their efficacy in removing aqueous pollutants. To overcome this challenge, this work introduces the production of covalently crosslinked CMCS-based beads containing SiO and poly(2-acrylamido-2-methylpropanesulfonic acid) (PAMPS). The porous composite beads not only possess remarkable stability under acidic conditions, but also have abundant active binding sites for adsorption.
View Article and Find Full Text PDFApplication of lanthanum-modified silk fibroin/polyvinyl alcohol film for highly selective defluoridation in brick tea infusion.
Int J Biol Macromol
January 2025
State Key Laboratory of Tea Plant Biology and Utilization, Joint Research Center for Food Nutrition and Health of IHM and Anhui Provincial Key Laboratory of Food Safety Monitoring and Quality Control, Anhui Agricultural University, Hefei 230036, PR China; College of Food and Nutrition, Anhui Agricultural University, Hefei 230036, PR China. Electronic address:
To mitigate the risk associated with water-soluble fluoride in tea and to have less influence on the contents of tea infusion, a highly selective lanthanum modified silk fibroin (SF) and polyvinyl alcohol (PVA) composite film (SF/PVA-La) was prepared to remove fluoride from brick tea infusion. Notably, SF/PVA-La could remove about 48 % of the fluoride from in brick tea infusion within 30 min. Importantly, the reduction in total tea polyphenols in brick tea did not exceed 10 %, and the reduction in caffeine was only 0.
View Article and Find Full Text PDFSubstrate-specific responses to mixing conditions in high-solids enzymatic hydrolysis: Insights from microcrystalline cellulose and dilute-acid pretreated corncob.
Int J Biol Macromol
January 2025
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest, Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, PR China. Electronic address:
This study investigates the mixing effects on the enzymatic hydrolysis of microcrystalline cellulose (MCC) and dilute-acid pretreated corncob substrates under high-solid conditions. Enzymatic hydrolysis experiments were conducted to assess cellulose conversion rates under varying mixing conditions (0, 50, 150, and 250 rpm) and solids loadings (5 %, 15 %, 25 %, and 35 %, w/v), and distinct physicochemical properties of the substrates were characterized. Additionally, the role of mixing conditions and solid loadings on cellulose hydrolysis kinetics and enzyme adsorption on both substrates and lignin were elucidated.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!