The first arsenic-based clathrate exhibiting superstructural ordering due to optimization of Au-As, As-As, and Ba-Au bonding is reported. BaAuAs crystallizes in a unique 2/ monoclinic clathrate structure. The synthesis, crystal and electronic structure, and transport properties are discussed.
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| http://dx.doi.org/10.1039/d1cc05167a | DOI Listing |
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