Understanding the unique behaviors of atomically dispersed catalysts and the origin thereof is a challenging topic. Herein, we demonstrate a facile strategy to encapsulate Pt species within Y zeolite and reveal the nature of selective hydrogenation over a Pt@Y model catalyst. The unique configuration of Pt@Y, namely atomically dispersed Pt stabilized by the surrounding oxygen atoms of six-membered rings shared by sodalite cages and supercages, enables the exclusive heterolytic activation of dihydrogen over Pt···O units, resembling the well-known classical Lewis pairs. The charged hydrogen species, i.e., H and H, are active reagents for selective hydrogenations, and therefore, the Pt@Y catalyst exhibits remarkable performance in the selective hydrogenation of α,β-unsaturated aldehydes to unsaturated alcohols and of nitroarenes to arylamines.
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http://dx.doi.org/10.1021/jacs.1c09535 | DOI Listing |
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