Herein, for the first time, we report a theoretical investigation on Indium nanoparticle-based surface enhanced fluorescence (SEF) from deep ultraviolet (UV) to near-infrared (NIR). In the beginning, the far- and near-field plasmonic properties of the Indium nanospheres of different sizes are studied to extract the wavelengths of lower and higher-order localized surface plasmon modes and the corresponding local electric field enhancement (EFE) values. Later, the dependence of the SEF enhancement with the separation between the fluorophore and nanoparticle (d), fluorescence, and excitation wavelengths is studied systematically. The role of the surrounding medium on plasmon mode wavelength and the SEF enhancement is also shown. Moreover, the effect of d and fluorescence wavelength on the average SEF enhancement is investigated. Finally, the variation in the plasmonic properties after thin dielectric coating on the surface of single Indium nanospheres is studied.
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http://dx.doi.org/10.1016/j.saa.2021.120603 | DOI Listing |
Chem Asian J
January 2025
Departamento de Química, Facultad de Ciencias, Universidad de Chile, Las Palmeras 3425, 7800003, Santiago, Chile.
Plasmonic materials can be utilized as effective platforms to enhance luminescent signals of luminescent metal nanoclusters (LMNCs). Both surface enhanced fluorescence (SEF) and shell-isolated nanoparticle-enhanced fluorescence (SHINEF) strategies take advantage of the localized and increased external electric field created around the plasmonic metal surface when excited at or near their characteristic plasmonic resonance. In this context, we present an experimental and computational study of different plasmonic composites, (Ag) Ag@SiO and (Au) Au@SiO nanoparticles, which were used to enhance the luminescent signal of Au nanoclusters coated with glutathione (GSH) molecule (AuGSH NCs).
View Article and Find Full Text PDFJ Environ Manage
January 2025
Key Laboratory of Agro-ecological Processes in Subtropical Region, Institute of Subtropical Agriculture, Chinese Academy of Sciences, Changsha 410125, China; Guangxi Key Laboratory of Karst Ecological Processes and Services, Huanjiang Observation and Research Station of Karst Ecosystems, Chinese Academy of Sciences, Huanjiang 547100, Guangxi, China. Electronic address:
In karst landscapes, where sustainable water management is increasingly challenged by drought-induced water scarcity, the adoption of road-based rainwater harvesting (RBWH) systems has emerged as a promising solution for improving water accessibility. Despite the growing implementation of such systems, the effectiveness of many RBWH projects in karst terrains remains suboptimal due to an inadequate understanding of runoff generation mechanisms associated with hilly road networks. This study focuses on quantifying the contributions of intercepted surface runoff (SR) and soil-epikarst lateral flow (SEF) from a newly exposed road-cut slope in a dolomite hillslope, with data collected across 156 rainfall events from May 2019 to May 2022.
View Article and Find Full Text PDFBiol Trace Elem Res
December 2024
Division of Agriculture and Environmental Science, School of Biosciences, University of Nottingham, Sutton Bonington Campus, Loughborough, Leicestershire, LE12 5RD, UK.
Dietary selenium (Se) is vital for human health and can be provided through consumption of Se-rich vegetables. Soil Se is often poorly available and so biofortification using Se-enriched fertilizers is used to enhance dietary intake. This study aimed to (a) evaluate the feasibility of biofortifying vegetables, commonly grown in the calcareous soils of Kurdistan, with a single application of Se (10 g ha) as selenate and, (b) trace the fate of applied Se using an enriched stable isotope, ⁷⁷Se.
View Article and Find Full Text PDFWe demonstrate an eight-wavelength-switchable single-frequency (SF) ultra-narrow linewidth erbium-doped fiber laser (EDFL). A switchable polarization-dependent eight-channel filter (S-PDECF), fabricated using femtosecond laser direct-writing technology, determines the eight wavelengths of the laser output, with four channels concentrated near 1530 nm and the other four near 1550 nm. A dual-coupler ring-based compound-cavity filter is utilized to achieve single-longitudinal-mode selection for the EDFL.
View Article and Find Full Text PDFMolecules
October 2024
Laboratorio de Biomoléculas y Salud Infantil, Instituto Nacional de Pediatría, Secretaría de Salud, Mexico City 04530, Mexico.
Triosephosphate isomerase (TPI) dysfunction is a critical factor in diverse pathological conditions. Deficiencies in TPI lead to the accumulation of toxic methylglyoxal (MGO), which induces non-enzymatic post-translational modifications, thus compromising protein stability and leading to misfolding. This study investigates how specific TPI mutations (E104D, N16D, and C217K) affect the enzyme's structural stability when exposed to its substrate glyceraldehyde 3-phosphate (G3P) and MGO.
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