Ionic surfactants as assembly crosslinkers triggered supramolecular membrane with 2D↔3D conversion under multiple stimulus.

Hypothesis: General strategies leading to 2D assemblies promise a significant step forward in the development of supramolecular materials with diversity and superiority. Considering molecular packing parameter indicates a connection between molecular geometry and aggregate morphology, we predict the introduction of ionic surfactants as assembly crosslinker would be endowed to develop a methodology of 2D supramolecular assembles.

Experiments: In this work, by introducing ionic surfactants such as sodium dodecylsulfate (SDS), the molecular packing parameter P in bolaamphiphile (A2G) system was increased, which successfully manipulated the transformation of the 3D vesicles into 2D membranes. This 2D membranes further showed excellent light and enzyme response, and thus 2D to 3D morphological conversion can be rationally controlled via UV/Vis light irradiation and alternate addition of β-CD and α-amylase. Significantly, the 2D feature revealed not only a remarkable fluorescence enhancement to luminescent molecules but also the ability to effectively remove pollutants from water through filtration.

Findings: We report a general and facile strategy for the construction of 2D supramolecular membranes, initiated by introducing ionic surfactants as assembly crosslinker to increase P. In the existence of stimulus response factors, 2D↔3D morphological conversion can be further controlled in a flexible manner, which opens up a new paradigm leading to interconvertible supramolecular materials.