This paper investigates size effects on the mechanical response of additively manufactured lattice structures based on a commercially available polylactic acid (PLA) polymer. Initial attention is focused on investigating geometrical effects in the mechanical properties of simple beams and cubes. Following this, a number of geometrically scaled lattice structures based on the body-centered cubic design were manufactured and tested in order to highlight size effects in their compression properties and failure modes. A finite element analysis was also conducted in order to compare the predicted modes of failure with those observed experimentally. Scaling effects were observed in the compression response of the PLA cubes, with the compression strength increasing by approximately 19% over the range of scale sizes investigated. Similar size-related effects were observed in the flexural samples, where a brittle mode of failure was observed at all scale sizes. Here, the flexural strength increased by approximately 18% when passing from the quarter size sample to its full-scale counterpart. Significant size effects were observed following the compression tests on the scaled lattice structures. Here, the compression strength increased by approximately 60% over the four sample sizes, in spite of the fact that similar failure modes were observed in all samples. Finally, reasonably good agreement was observed between the predicted failure modes and those observed experimentally. However, the FE models tended to over-estimate the mechanical properties of the lattice structures, probably as a result of the fact that the models were assumed to be defect free.
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http://dx.doi.org/10.3390/polym13223967 | DOI Listing |
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January 2025
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China.
Polymer composite materials encounter considerable challenges in sustaining superior tribological properties at high rotational speeds. Inspired by the microstructure of dragonfly wings, a novel thermally stable and ambient pressure curing poly(urea-imide) resin (PURI) with excellent tribological properties has been eco-friendly synthesis using bio-based greener solvents. Furthermore, The PURI composites enhanced with polyether ether ketone (PEEK) and Polytetrafluoroethylene (PTFE) blended fabrics demonstrate excellent mechanical, with tensile strengths exceeding 175 MPa.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Hangzhou International Innovation Institute, Beihang University, Hangzhou, 311115, P. R. China.
In sodium-ion batteries, the layered transition metal oxides used as cathode often experience interlayer sliding of interlayer spacing and lattice variations during charge/discharge, leading to structural damage and capacity degradation. To address this challenge, a La doping strategy guided by Bayesian optimization has been employed to prepare the high-performance O3-NaNiMnCuLaO (NMCL) cathode material. Density functional theory calculations reveal that the O 2p orbital overlaps with the t orbital of transition metals in NMCL, facilitating the formation of Na-O-La bonds and promoting the oxygen redox reaction kinetics.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
DST Unit of Nanoscience (DST UNS) and Thematic Unit of Excellence (TUE), Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India.
Clathrate hydrates (CHs) are believed to exist in cold regions of space, such as comets and icy moons. While spectroscopic studies have explored their formation under similar laboratory conditions, direct structural characterization using diffraction techniques has remained elusive. We present the first electron diffraction study of tetrahydrofuran (THF) and 1,3-dioxolane (DIOX) CHs in the form of nanometer-thin ice films under an ultrahigh vacuum at cryogenic temperatures.
View Article and Find Full Text PDFSmall
January 2025
School of Materials Science and Engineering, Harbin Institute of Technology, Shenzhen, 518055, China.
The development of efficient hydrogen evolution reaction (HER) catalysts is crucial for water electrolysis. Currently, Ru-based catalysts are considered top contenders, but issues with stability, activity, and cost remain. In this work, RuNi alloys possessing a solid solution structure within the Ru lattice are prepared via straightforward electrodeposition on various substrates and assessed as HER catalysts in alkaline media.
View Article and Find Full Text PDFAdv Mater
January 2025
Center for Hybrid Organic-Inorganic Semiconductors for Energy, Golden, Colorado, 80401, USA.
Recent activity in the area of chiroptical phenomena has been focused on the connection between structural asymmetry, electron spin configuration and light/matter interactions in chiral semiconductors. In these systems, spin-splitting phenomena emerge due to inversion symmetry breaking and the presence of extended electronic states, yet the connection to chiroptical phenomena is lacking. Here, we develop an analytical effective mass model of chiral excitons, parameterized by density functional theory.
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