The study investigated the toxicity effects of 'form specific' engineered nanomaterials (ENMs) and ions released from nano-enabled products (NEPs), namely sunscreens, sanitisers, body creams and socks on , , and . Additionally, risk estimation emanating from the exposures was undertaken. The ENMs and the ions released from the products both contributed to the effects to varying extents, with neither being a uniform principal toxicity agent across the exposures; however, the effects were either synergistic or antagonistic. and were the most sensitive and least sensitive test organisms, respectively. The most toxic effects were from ENMs and ions released from sanitisers and sunscreens, whereas body creams and sock counterparts caused negligible effects. The internalisation of the ENMs from the sunscreens could not be established; only adsorption on the biota was evident. It was established that ENMs and ions released from products pose no imminent risk to ecosystems; instead, small to significant adverse effects are expected in the worst-case exposure scenario. The study demonstrates that while ENMs from products may not be considered to pose an imminent risk, increasing nanotechnology commercialization may increase their environmental exposure and risk potential; therefore, priority exposure cases need to be examined.
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http://dx.doi.org/10.3390/ijms222212468 | DOI Listing |
Environ Sci Nano
September 2024
Instituto de Catálisis y Petroleoquímica, ICP-CSIC Marie Curie 2 28049-Madrid Spain
Methanol probe chemisorption quantifies the number of reactive sites at the surface of engineered nanomaterials, enabling normalization per reactive site in reactivity and toxicity tests, rather than per mass or physical surface area. Subsequent temperature-programmed surface reaction (TPSR) of chemisorbed methanol identifies the reactive nature of surface sites (acidic, basic, redox or combination thereof) and their reactivity. Complementary to the methanol assay, a dithiothreitol (DTT) probe oxidation reaction is used to evaluate the oxidation capacity.
View Article and Find Full Text PDFNanoImpact
April 2024
Materials Measurement Science Division, National Institute of Standards and Technology, 100 Bureau Drive, MS-8372, Gaithersburg, MD 20899, United States.
To ensure the safe use of materials, one must assess the identity and quantity of exposure. Solid materials, such as plastics, metals, coatings and cements, degrade to some extent during their life cycle, and releases can occur during manufacturing, use and end-of-life. Releases (e.
View Article and Find Full Text PDFComput Struct Biotechnol J
December 2024
Laboratory of Environmental Chemoinformatics, Faculty of Chemistry, University of Gdansk, Wita Stwosza 63, 80-308 Gdansk, Poland.
Numerous processes such as solubility, agglomeration/aggregation, or protein corona formation may change over time and significantly affect engineered nanomaterial (ENM) structure, property, and availability, resulting in their reduced or increased toxicological activity. Therefore, understanding the dynamics of these processes is essential for assessing and managing the risks of ENMs during their lifecycle, ensuring safety by design. Of these processes, the importance of solubility (i.
View Article and Find Full Text PDFEnviron Res
February 2024
College of Resources and Environment, Key Laboratory of Agricultural Environment in Universities of Shandong, Shandong Agricultural University, Taian, 271018, China.
Engineered nanomaterials (ENMs) are inevitably released into the environment with the exponential application of nanotechnology. Parts of ENMs eventually accumulate in the soil environment leading to potential adverse effects on soil ecology, crop production, and human health. Therefore, the safety application of ENMs on soil has been widely discussed in recent years.
View Article and Find Full Text PDFPlant Physiol Biochem
November 2023
Key Laboratory of Sugarcane Biotechnology and Genetic Improvement (Guangxi), Ministry of Agriculture and Rural Affairs, Guangxi Key Laboratory of Sugarcane Genetic Improvement, Sugarcane Research Institute, Guangxi Academy of Agricultural Sciences, Nanning, 530007, Guangxi, China. Electronic address:
Fluoride (F) stress is one of the major environmental pollutant, affecting plant growth, development and production, globally. Acquisition of eco-friendly F stress reliever seems to be the major concern these days. Consequently, application of engineered nanomaterials (ENMs) has been increasing to improve agri-economy.
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