Macroporous chitin microspheres prepared by surfactant micelle swelling strategy for rapid capture of lead (II) from wastewater.

Heavy metal pollution of water source continues to be one of the most serious environmental problems which have attracted major global concern. Here, a macroporous chitin microsphere is prepared by surfactant micelle swelling strategy followed by modification with tetraethylenepentamine for Pb removal from wastewater. The resultant adsorbent not only exhibits fast adsorption kinetic (>80% of its equilibrium uptake within 20 min) but also has high adsorption capacity of 218.4 ± 6.59 mg/g and excellent reusability (>75% of its initial adsorption capacity after five adsorption/desorption cycles). More importantly, under the continuous operating mode, the adsorbent can treat about 39,000 kg water/kg adsorbent, and the Pb concentration decreases from 2000 μg/L to smaller than 10 μg/L, meeting the drinking water standard recommended by the World Health Organization (10 μg/L). All results indicate that the tetraethylenepentamine-modified macroporous chitin microspheres have great potential in the treatment of heavy metal contamination.