AI Article Synopsis
- The text discusses a method for exchanging boryl groups between alkenylboranes and diboron reagents, suggesting this process occurs via a stereospecific cross-metathesis pathway.
- This exchange results in the formation of mixed diboron reagents, which are essential for various chemical reactions.
- Using Density Functional Theory (DFT) calculations, a mechanism for achieving stereocontrol in this cross-metathesis involving both symmetric and asymmetric diboron reagents is proposed.
Article Abstract
Exchange of boryl moieties between alkenylboranes and diboron reagents has been postulated as a stereospecific cross-metathesis pathway with concomitant formation of mixed diboron reagents. DFT calculations propose a mechanism for the stereocontrolled C(sp)-B/B'-B' cross-metathesis with both symmetric and non-symmetric diboron reagents.
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| http://dx.doi.org/10.1039/d1cc05815k | DOI Listing |
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