We describe the synthesis of [-PhP(O)(CH)SbPh] ([2]), an intramolecularly base-stabilized stibonium Lewis acid which was obtained by reaction of [-PhP(CH)SbPh] with NOBF. This cation reacts with fluoride anions to afford the corresponding fluorostiborane -PhP(O)(CH)SbFPh, the structure of which indicates a strengthening of the PO → Sb interaction. When deployed in fluoride-containing POPC unilamellar vesicles, [2] behaves as a potent fluoride anion transporter whose activity greatly exceeds that of [PhSb].
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d1dt03370k | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Home-use agents in the treatment of dentin hypersensitivity: clinical effectiveness evaluation with different measurement methods.
Clin Oral Investig
January 2025
Faculty of Dentistry, Department of Restorative Dentistry, Çanakkale Onsekiz Mart University, Çanakkale, 17100, Turkey.
Objectives: This study aimed to evaluate the effectiveness of home-use desensitizing agents over an 8-week period by comparing them using different measurement methods.
Methods: A randomized, controlled clinical trial was conducted with 180 individuals aged between 18 and 70 who clinically diagnosed dentin hypersensitivity (DH) in two or more non-adjacent teeth. Subjects who met the inclusion criteria (n = 164) were randomly allocated into five test groups-using Casein phosphopeptide-amorphous calcium phosphate (CPP-ACP), Arginine, Novamin, Propolis, and Potassium nitrate-and a control group using standard fluoride toothpaste.
Fluoride binding-modulated supramolecular chirality of urea-containing triarylamine and its photo-manifestation.
Nanoscale
January 2025
Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, No. 2 ZhongGuanCun BeiYiJie, 100190, Beijing, P. R. China.
In recent years, the regulation of anion-mediated chiral assemblies has gained significant interest. This study investigated the modulation of supramolecular chiroptical signals and chiral assembled structures in a triarylamine system containing a urea moiety through fluoride ion-urea bond interactions, aiming to understand the chiral sense amplification in supramolecular assemblies. Chiral triarylamine derivatives containing urea or amide units were synthesized and the self-assemblies were examined in the absence and presence of fluoride ions.
View Article and Find Full Text PDFCathode Design Based on Nitrogen Redox and Linear Coordination of Cu Center for All-Solid-State Fluoride-Ion Batteries.
J Am Chem Soc
January 2025
Graduate School of Human and Environmental Studies, Kyoto University, Sakyo, Kyoto 606-8501, Japan.
All-solid-state fluoride-ion batteries (FIBs) have attracted extensive attention as candidates for next-generation energy storage devices; however, promising cathodes with high energy density are still lacking. In this study, CuN is investigated as a cathode material for all-solid-state fluoride-ion batteries, which offers enough anionic vacancies around the 2-fold coordinated Cu center for F intercalation, thereby enabling a multielectron-transferred fluorination process. The contribution of both cationic and anionic redox to charge compensation, in particular, the generation of molecular nitrogen species in highly charged states, has been proved by several synchrotron-radiation-based spectroscopic technologies.
View Article and Find Full Text PDFFormulation of different concentrations of nanosilver fluoride incorporated dentifrices, evaluation of its cytotoxicity and antimicrobial effect on Streptococcus mutans.
J Indian Soc Pedod Prev Dent
October 2024
Department of Pediatric and Preventive Dentistry, Santosh Deemed to be University, Santosh Dental College and Hospital, Ghaziabad, Uttar Pradesh, India.
Article Synopsis
- The study investigates the effectiveness and safety of dentifrices containing Nano silver fluoride (NSF) against the bacteria Streptococcus mutans, which causes tooth decay.
- Researchers synthesized NSF particles and created dentifrices with varying concentrations of NSF, assessing their antimicrobial properties using an agar diffusion method and cytotoxicity on mouse macrophage cells.
- Results showed that NSF dentifrices inhibited bacterial growth effectively while also evaluating their impact on cell viability to ensure safety for use in oral health products.
Comparative evaluation of silver diamine fluoride, glass ionomer cement, and calcium hydroxide for indirect pulp therapy in young permanent molars: A randomized controlled trial.
J Indian Soc Pedod Prev Dent
October 2024
Department of Paediatric and Preventive Dentistry, T.P.C.T's Terna Dental College, Navi Mumbai, Maharashtra, India.
Objectives: Comparative evaluation of indirect pulp therapy (IPT) with silver diamine fluoride (SDF), Type VII glass ionomer cement (GIC), and calcium hydroxide (Ca(OH)2) in young permanent molars.
Materials And Methods: This was randomized controlled trial, in which 45 children with 60 young permanent first molars were allocated as; Group A: IPT with SDF, Group B: Type VII GIC, and Group C: Ca(OH)2. Clinical and radiographic evaluation and comparison was done at baseline, 3, 6, 12 months.
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!